1-Silantranyl Nitrate

摘要

A method of synthesis of 1-silatranyl nitrate O2NOSi(OCH2CH2)3N based on the reaction of 1-hydrosilatrane with mercury nitrate in the acetonitrile medium was developed. The structure of the synthesized 1-silatranyl nitrate, mp 227°C, was confirmed by elemental analysis, ~1H, ~(13)C, and ~(29)Si NMR spectoscopy, infrared spectroscopy, and mass spectrometry. Silatranyl nitrate previously described in the literature as yellowish viscous oil apparently contains impurities preventing its crystallization.