Synthesis and Structure of Palladium(II) and Copper(II) Complexes with Chiral Bis-α-aminooximes Containing (+)-3-Carene or (+)-Limonene Fragments and 4,4'-Methylenedianiline Linker. Crystal Structure of the Complex [Cu(i-PrOH)Cl2(μ-H2L~3)CuCl2H2O]

摘要

Coordination compounds Pd2(H2L~2)Cl4 (I), Cu2(H2L~2)Cl4 (II), Pd2(H2L~3)CU (III), and Cu2(H2L~3) Cl4 (IV), where H2L~2 and H2L~3 are chiral bis-α-aminooxime ligands consisting of (+)-3-carene or (+)-limonene fragments and 4,4'-methylenedianiline linker, were synthesized and examined by NMR, ESR, and IR spectroscopy. The structure of [Cu(i-PrOH)Cl2(μ-H2L~3)CuCl2·H2O] (V) was determined by X-ray analysis.