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Low-temperature synthesis of WO3 nanolamella and their sensing properties for xylene

机译:WO3纳米片的低温合成及其对二甲苯的传感性能

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摘要

Tungsten trioxides (WO3) are an important class of n-type semiconductor oxide materials with a wide bandgap. In this work, nanolamella of tungsten oxides have been successfully synthesized by a simple, facile and cost-effective route starting from Na2WO4 and subsequent calcination at 300 degrees C. The structure and morphology of the nanolamella were characterized by X-ray diffraction (XRD) scanning electron microscopy (SEM), Fourier Transform Infrared Spectroscopy (FTIR) and photoluminescence (PL), respectively. The morphologies of the prepared products can be tailored by changing the calcination temperature. The obtained WO3 products were investigated as sensitive materials for the detection of xylene. On the basis of gas sensing tests, the sensor using WO3 nanolamella after annealing at 300 degrees C for 2 h exhibited better gas sensing properties. The maximum response reached 47 to 100 ppm of xylene at 280 degrees C. These results indicated that the gas sensors based on WO3 nanolamella express high and fast response and recovery characteristics to xylene, and the WO3 nanolamella are promising sensitive materials for xylene detecting.
机译:三氧化钨(WO3)是一类重要的带隙宽的n型半导体氧化物材料。在这项工作中,氧化钨纳米薄片已经成功地通过一种简单,便捷且具有成本效益的途径从Na2WO4开始并随后在300摄氏度下煅烧而成功合成。该纳米薄片的结构和形态通过X射线衍射(XRD)表征扫描电子显微镜(SEM),傅立叶变换红外光谱(FTIR)和光致发光(PL)。可以通过改变煅烧温度来调整所制备产品的形态。研究了获得的WO3产品作为检测二甲苯的敏感材料。根据气体传感测试,使用WO3纳米片的传感器在300摄氏度下退火2小时后,表现出更好的气体传感性能。在280摄氏度下,二甲苯的最大响应达到47至100 ppm。这些结果表明,基于WO3纳米薄片的气体传感器表现出对二甲苯的高,快速响应和回收特性,而WO3纳米薄片是用于二甲苯检测的有希望的敏感材料。

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