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Surface fitting - new tool for spectrally resolved thermoluminescence analysis

机译:表面拟合-用于光谱解析热发光分析的新工具

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摘要

Numerical deconvolution and curve-fitting algorithms are routinely used for the analysis of complex thermoluminescence (TL) data. This approach is generally not suitable for advanced TL measurements utilizing simultaneous detection of wavelength and intensity of the emitted light. In this paper we present new 'surface fitting' algorithm. Spectrally resolved TL surface is numerically deconvoluted for individual surface peaks corresponding to trap levels and recombination centres. This technique allows simultaneous determination of activation energies of traps and the emission bands associated with recombination centres utilizing all measured data points. To demonstrate possibilities of the method we applied the algorithm to numerical deconvolution of spectrally resolved TL data measured for high-sensitive LiF:Mg,Cu,P thermoluminescent detector. (C) 2004 Elsevier Ltd. All rights reserved.
机译:通常使用数值解卷积和曲线拟合算法来分析复杂的热发光(TL)数据。这种方法通常不适用于同时检测发射光的波长和强度的高级TL测量。在本文中,我们提出了新的“曲面拟合”算法。对于与捕集能级和重组中心相对应的单个表面峰,对光谱分辨的TL表面进行数值解卷积。该技术允许利用所有测得的数据点同时确定阱的活化能和与重组中心相关的发射带。为了证明该方法的可能性,我们将该算法应用于为高灵敏度LiF:Mg,Cu,P热发光检测器测量的光谱分辨TL数据的数值反卷积。 (C)2004 Elsevier Ltd.保留所有权利。

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