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INVESTIGATION OF TIO_2-ADDED REFRACTORY BRICK PROPERTIES FROM CALCINED MAGNESITE RAW MATERIAL

机译:煅烧菱镁矿原料对TIO_2耐火砖性能的研究

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This paper is the second part of a study on recycling magnesite and chromite ore (in the 0-10~-3m fraction) powder, which remains as a production process waste. In this work, 90 percent magnesite-10 percent chromite composition was used as a brick composition. Compaction pressure, sintering temperature, ratio of TiO_2 addition, and influence of bonding type on refractory properties were examined. In refractory brick production, one of the most important parameters that affects the properties of the product is the particle size distribution of the blend. Experiments show that using a magnesite particle size of-10~-3 m and a chromite particle size of-63X10~-6m affects the properties of the product in a positive way. Experiment blends with the particle sizes selected above were used. Magnesite ore was used in experiments after calcination at 1200 deg for four hours. In the experiments we mention, MgCl_2 and MgSO_4 solutions were used as a bonding agent, as a result of which a 6 percent bonding ratio of MgCl_2 and MgSO_4 solutions was determined as optimum. The effect of compacting pressure on the refractory properties was studied, and the optimum compacting pressure was determined as 180 MPa. For bricks prepared using calcined magnesite, the optimum sintering temperature was found to be 1750 deg. The positive effect of TiO_2 addition on the magnesite chrome refractory brick structure has been reported in the literature. Thus, 1, 3, 5, and 7 wt. percent TiO_2 ratios were used in the blend, and the refractory properties were positively affected by the 3 percent TiO_2 addition. Taking the result of the MgCl_2 and MgSO_4 bonding solution into consideration, it is clear that the refractory properties of brick can be improved by using a mixture of MgCl_2 and MgSO_4 bonding solutions. In light of the above concept, bonding mixtures with 1:3,1:5, and 1:10 ratios were prepared, and these bonding mixtures were studies as a bonding material. The experimental results show that the cold crushing strength (CCS) and volume density of bricks increase, whereas the porosity decreases when a 1:5 ratio of MgCl_2 and MgSO_4 in the bonding mixture and 3 percent TiO_2 addition were used. Microstructural study of the produced bricks was done using scanning electron microscope (SEM). In addition to this, the phases forming the structure of brick were examined via x-ray diagrams of the material. In bricks where a mixture of a 1:5 MgCl_2: MgSO_4 bonding solution was used as bonding agent and 3 percent TiO_2 was added, spinel (magnochromite (MgCr_2O_4)), magnesium orthotitanate (Mg_2TiO_4), monticellite (CaMgSiO_4), and forsterite (Mg_2SiO_4) phases were found. The perovskite phase was not observed during the experimental study.
机译:本文是对镁砂和亚铬铁矿粉(0-10〜-3m级)粉体进行回收研究的第二部分,这些粉体仍作为生产过程中的废料。在这项工作中,将90%菱镁矿-10%亚铬酸盐组合物用作砖块组合物。研究了压实压力,烧结温度,TiO_2添加比例,粘结方式对耐火性能的影响。在耐火砖的生产中,影响产品性能的最重要参数之一是混合物的粒度分布。实验表明,使用菱镁矿粒径为-10〜-3 m和亚铬酸盐粒径为-63X10〜-6m会对产品的性能产生积极的影响。使用具有以上选择的粒度的实验混合物。菱镁矿在1200度煅烧4小时后用于实验。在我们提到的实验中,将MgCl_2和MgSO_4溶液用作粘合剂,结果确定MgCl_2和MgSO_4溶液的6%的结合率为最佳。研究了压实压力对耐火性能的影响,确定最佳压实压力为180 MPa。对于使用煅烧菱镁矿制备的砖,发现最佳烧结温度为1750度。已有文献报道了TiO_2的添加对菱镁矿铬耐火砖结构的积极影响。因此,1、3、5和7重量%。共混物中使用了5%的TiO_2比率,而TiO_2加入3%则对耐火性能产生了积极的影响。考虑到MgCl_2和MgSO_4键合溶液的结果,很明显,通过使用MgCl_2和MgSO_4键合溶液的混合物可以改善砖的耐火性能。根据上述概念,制备了具有1:3、1:5和1:10比例的粘结混合物,并且研究了这些粘结混合物作为粘结材料。实验结果表明,当混合料中MgCl_2和MgSO_4的比例为1:5且TiO_2的添加量为3%时,砖的抗压碎强度(CCS)和体积密度增加,而孔隙率降低。使用扫描电子显微镜(SEM)对制成的砖进行了微观结构研究。除此之外,还通过材料的X射线图检查了形成砖结构的相。在使用1:5 MgCl_2:MgSO_4粘结溶液的混合物作为粘结剂并添加3%TiO_2的砖中,尖晶石(镁铬铁矿(MgCr_2O_4)),原钛酸镁(Mg_2TiO_4),蒙脱石(CaMgSiO_4)和镁橄榄石(Mg_2SiO_4 )相。在实验研究中未观察到钙钛矿相。

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