Synthesis, photophysics, and electrochemistry of dinuclear cadmium(II) diimine complexes with bridging chalcogenolate ligands. X-Ray crystal structures of [(phen)(2)Cd(mu-SC6H4CH3-p)](2)(PF6)(2) and [(phen)(2)Cd(mu-SeC6H5)](2)(PF6)(2)

摘要

A new series of luminescent dinuclear six-coordinate cadmium(II) diimine complexes with bridging chalcogenolate ligands has been synthesized and characterized, and shown to exhibit interesting photophysical and electrochemical properties. The X-ray crystal structures of [(phen)(2)Cd(mu-SC6H4CH3-p)](2)(PF6)(2) (11) and [(phen)(2)Cd(mu-SeC6H5)](2)(PF6)(2) (12) have been determined. [References: 68]