Окисление окиси утлерода на закиси никеля и твердых растворах LixNi1−1O

摘要

It has been shown that lithium incorporated into a NiO lattice increases the activation energy of CO oxidation by 6 kcal/mol, decreases the binding energy of surface oxygen by 8–9 kcal/mol, and lowers the Fermi level by 7 kcal/mol. The rate-determining step of the reaction is assumed to be the interaction of carbon monoxide with oxygen in the adsorbed layer with the participation of a free electro