N-doped carbon quantum dots for TiO_2-based photocatalysts and dye-sensitized solar cells

摘要

N-doped nanostructured carbon materials have attracted much attention because the doping can induce new unique physical and chemical properties of carbon. In this study, we report, for the first time, that N-doped carbon quantum dots (NCQDs) can combine with rutile TiO_2 and form NCQDs/TiO2 hierarchical microspheres assembled by nanorods with enhanced photocatalytic activities under visible light irradiation. As a result, the pseudo-first-order reaction constant for the degradation of rhodamine B (RhB) on NCQDs/TiO2 (0.11min~(-1)) is 215.7, 7.3 and 1.3 times much larger than that of NCQDs (0.00051min-1), TiO2 (0.015min~(-1)), and CQDs/TiO2 (0.086min~(-1)), respectively. The functions of NCQDs were discussed and a new synergistic photosensitized mechanism was proposed for the degradation of RhB on the as-synthesized NCQDs/TiO_2 nanocomposites based on the experimental results. NCQDs were also applied as metal-free sensitizers in dye-sensitized solar cells (DSSCs) for the first time. A preliminary study shows that under one sun illumination (AM 1.5), the open circuit voltage and fill factor values reach 0.46V and 43%, respectively, achieving a power conversion efficiency of 0.13% in the proof-of-concept TiO_2-based DSSCs device. The performance of NCQDs sensitized solar cells surpasses that of N-free counterpart as well. N-doping lowered the work function of CQDs, which was responsible for enhanced photocatalytic activity of NCQDs/TiO_2 and better NCQDs sensitized TiO_2-based solar cell performance.