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Two New Phenolic Glycosides from Hypoxis aurea Lour

机译:两种来自金黄色葡萄球菌的新酚类糖苷

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Plants of the genus Hypoxidaceae are widely distributed in Torrid Zone in the world, and previous studies of the genus by our group revealed that it mainly contain phenolic glycosides. Hypoxis aurea Lour, belongs to the genus Hypoxidaceae, called as 'xiao jin mei' to treat hernia and warm kidney in China and mainly distributed over the southern of China, south east of Asia and Japan. Chemical investigation of the rhizomes of H. aurea toward potentially bioactive secondary metabolites from this genus leading to the isolation of two new phenolic glycosides, aureaside A (1) and aureaside B (2), together with seven known compounds, curculigoside I (3), orcinol glucoside (4), curcapital (5), cimifugin prim-O-β-D-glucopyranoside (6), 2-O-β-D-apiofuranosyl (1β6)-O-β-D-glucopyranoside (7), (2R,5S)-bomane-2,5-diol-2-O→-D-glucopyranoside (8), and bornyl 7-O-β-D-apio-D-furanosyl (1→6)-O-β-D-glucopyranoside (9) as shown in Figure 1. Their structures were elucidated on the basis of spectroscopic analysis and comparing spectral data with those known compounds reported in literatures. All these compounds were found in this plant for the first time. In this paper we reported the isolation and structural elucidation of two new compounds from H. aurea Lour.
机译:Hypoxidaceae属的植物广泛分布于世界Torrid Zone,我们小组先前对该属的研究表明,它主要含有酚类糖苷。 Hypoxis aurea Lour属于Hypoxidaceae属,被称为“小金妹”,用于治疗中国的疝气和温暖的肾脏,主要分布在中国南部,亚洲东南部和日本。从该属中对金黄色葡萄球菌的根茎向可能具有生物活性的次生代谢产物进行化学研究,从而导致分离出两种新的酚类糖苷,金黄色葡萄苷A(1)和金黄色苷B(2),以及七种已知化合物,仙茅苷I(3)。 ,蓖麻酚糖苷(4),首都医院(5),cimifuginprim-O-β-D-吡喃葡萄糖苷(6),2-O-β-D-呋喃呋喃糖基(1β6)-O-β-D-吡喃葡萄糖苷(7), (2R,5S)-2,5-二醇-2-O→-D-吡喃葡萄糖苷(8R)和冰片基7-O-β-D-api-D-呋喃糖基(1→6)-O-β -D-吡喃葡萄糖苷(9)如图1所示。在光谱分析的基础上阐明了它们的结构,并将光谱数据与文献中报道的已知化合物进行了比较。所有这些化合物都是在该植物中首次发现的。在本文中,我们报道了来自金黄色葡萄球菌的两种新化合物的分离和结构解析。

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