Multiwall carbon nanotube supported poly(3,4-ethylenedioxythiophene)/manganese oxide nano-composite electrode for super-capacitors

摘要

MWCNT-PSS/PEDOT/MnO_2 nano-composite electrodes were fabricated by generating pseudo-capacitive poly(3,4-ethylenedioxythiophene) (PEDOT)/MnO_2 nano-structures on poly(styrene sulfonate) (PSS) dispersed multiwalled carbon nanotubes (MWCNTs). PSS dispersed MWCNTs (MWCNT-PSS) facilitated the growth of PEDOT and MnO_2 into nano-rods with large active surface area and good electrical conductivity. The ternary MWCNT-PSS/PEDOT/MnO_2 nano-composite electrode was studied for the application in super-capacitors, and exhibited excellent capacitive behavior between -0.2 V and 0.8 V (vs. saturated Ag/AgCl electrode) with high reversibility. Specific capacitance of the nano-composite electrode was found as high as 375 Fg~(-1). In contrast, specific capacitance of MWCNT-PSS/MnO_2 and MWCNT-PSS nano-composite electrodes is 175 Fg~(-1) and 15 Fg~(-1). respectively. Based on cyclic voltammetric studies and cycle-life tests, the MWCNT-PSS/PEDOT/MnO_2 nano-composite electrode gave a highly stable and reversible performance up to 2000 cycles. Our studies demonstrate that the synergistic combination of MWCNT-PSS/PEDOT and MnO_2 has advantages over the sum of the individual components.