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Sr_4Al_(14)O_(25):Eu~(2+) Nanophosphor Synthesized with Salted Sol-Gel Method

机译:盐溶胶-凝胶法合成Sr_4Al_(14)O_(25):Eu〜(2+)纳米磷光体

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摘要

Nanophosphors of Sr_4Al_(14)O_(25):Eu~(2+) were synthesized with a salted sol-gel method. X-ray diffraction spectrum showed that Sr_4Al_(14)O_(25) was obtained after it was sintered at 900 deg C for 2 h. Sr4Ali4025:Eu2+ nanophosphor was a nestlike nanofiber with an average diameter of 10-20 nm under a scanning electron microscope. Emission peaks of Eu~(2+) 4f~7-4f~65d~1 transitions were found at 487 and 408 nm corresponding to two Eu2+ sites in Sr_4Al_(14)O_(25). Energy transfer between Eu~(2+) in two different sites was reduced to one-half the number that were made by solid-state reaction.
机译:采用盐溶胶-凝胶法合成了Sr_4Al_(14)O_(25):Eu〜(2+)纳米荧光粉。 X射线衍射光谱表明,Sr_4Al_(14)O_(25)在900℃烧结2 h后得到。 Sr4Ali4025:Eu2 +纳米荧光粉为巢状纳米纤维,在扫描电子显微镜下平均直径为10-20 nm。在487和408 nm处发现了Eu〜(2+)4f〜7-4f〜65d〜1跃迁的发射峰,对应于Sr_4Al_(14)O_(25)中的两个Eu2 +位点。 Eu〜(2+)在两个不同位置之间的能量转移减少到固态反应的一半。

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