Preparation and photoluminescence properties of Sr_4Al_(14)O_(25):Eu~(2+) phosphors synthesized via the microemulsion route

摘要

Strontium aluminate phosphors doped with europium ions (Sr_4Al_(14)O_(25):Eu~(2+)) were successfully synthesized via the microemulsion route. In comparison with the traditional solid-state reaction process, the calcination temperature of Sr_4Al_(14)O_(25):Eu~(2+) phase in this study was lowered to 1,100℃ when the flux was added. In addition, the particle size of Sr_4Al_(14)O_(25):Eu~(2+) phosphors prepared via the microemulsion route was greatly reduced to 50 nm. The lowered synthesis temperature and reduced particle size are attributed to nano-scaled micelles formed in the microemulsion system. The emission and excitation intensity of Sr_4Al_(14)O_(25):Eu~(2+) phosphors were increased with an increase in the synthesis temperature. In addition, the rise in the calcination temperature lowered the afterglow characteristics of Sr_4Al_(14)O_(25):Eu~(2+) phosphors. The microemulsion route was demonstrated to be an more effective process than the solid-state reaction process for preparing Sr_4Al_(14)O_(25):Eu~(2+) phosphors.