Analysis of Trace Levels of Ge Transferred to Si Wafer Surfaces during SiGe Wafer Processing

摘要

Effects of trace levels of Ge transferred to Si surfaces during thermal processing of SiGe wafers are presented here. Si wafers were coprocessed in an oxidation furnace with SiGe relaxed graded buffer layers grown on Si. Total X-ray fluorescence measurements on Si wafers showed Ge concentrations in varying degrees depending on oxidation temperature, time, and the number of coprocessed SiGe wafers. The Ge concentration level increases with increase of oxidation time, temperature, and SiGe wafer quantity. It was also observed that the furnace shows "memory" of the process during subsequent process runs. A chlorine-based purge of the oxidation tube after processing SiGe wafers helps reduce the Ge concentration remarkably. Metal oxide semiconductor capacitance and gate leakage characterization were used to evaluate the effects of transferred Ge on the gate oxide. The interface state density is marginally higher on Si wafers with transferred Ge.