Ni(III) complex of an N-confused porphyrin inner C-oxide

Xiao ZW.; Patrick BO.; Dolphin D.

首页> 外文期刊>Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics >Ni(III) complex of an N-confused porphyrin inner C-oxide

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Ni(III) complex of an N-confused porphyrin inner C-oxide

机译：N杂卟啉内部C-氧化物的Ni（III）配合物

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novel, structurally characterized Ni(III) complex of an N-confused porphyrin inner C-oxide has been synthesized from the oxidation of a Ni(II) N-confused porphyrin using OsO4. Crystal data: C53H40N5NiO.CH2Cl2, monoclinic, space group P2/a (No. 13), a = 21.229(1) Angstrom, b = 8.6451(5) Angstrom, c = 25.762(2) Angstrom, 93.004(3)degrees, V = 4721.6(5) Angstrom(3), and Z = 4. [References: 15]

机译：通过使用OsO4对Ni（II）与N杂化的卟啉进行氧化，合成了一种新型的，结构复杂的，与N杂化的卟啉内部具有C-氧化物的Ni（III）配合物。晶体数据：C53H40N5NiO.CH2Cl2，单斜晶，空间群P2 / a（No. 13），a = 21.229（1）埃，b = 8.6451（5）埃，c = 25.762（2）埃，93.004（3）度， V = 4721.6（5）埃（3），Z =4。[参考：15]

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《Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics》 |2003年第25期|共3页
作者
Xiao ZW.; Patrick BO.; Dolphin D.;
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正文语种 eng
中图分类化学;
关键词
Structural characterization; Nickel(ii); Metalloporphyrins; Chemistry; Oxidation; Isomer;

机译：结构表征;镍（ii）;金属卟啉;化学;氧化;异构体;

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1. Ni(III) complex of an N-confused porphyrin inner C-oxide [J] . Xiao ZW., Patrick BO., Dolphin D. Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2003,第25期

机译：N杂卟啉内部C-氧化物的Ni（III）配合物
2. Molecular structures of Cu(II), Rh(III) complexes of 2-N substituted N-confused porphyrin inner C-oxide [J] . Lin W.-C., Hsaio D.-Z., Chang W.-P., Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2012,第Null期

机译：2-N取代的N-混淆的卟啉内部C-氧化物的Cu（II），Rh（III）配合物的分子结构
3. Organometallic Group 11 (Cu~(III), Ag~(III), Au~(III)) Complexes of a trans-Doubly N-Confused Porphyrin: An "Expanded Imidazole" Structural Motif [J] . Jiaying Yan, Yufeng Yang, Masatoshi Ishida, Chemistry: A European journal . 2017,第47期

机译：有机金属基团11（Cu〜（III），Ag〜（III），Au〜（III），Au〜（III））复合物的逆时间N-混淆卟啉：“膨胀咪唑”结构基序
4. Sensitised Ln (III) Emission and Excited State Dynamics of Cofacial 'Pacman' Porphyrin Terpyridine Complexes [C] . Jane Y. Liew, Matthias Schwalbe, Evan G. Moore Rare Earth Research Conference . 2019

机译：Cofacial'Pacman'Porphyrin Terpyridines复合物的敏感LN（III）发射和激发状态动态
5. Model complexes as probes of heme and nonheme enzymatic mechanisms: (1) Ferric peroxo porphyrin complexes as mimics of P450 enzymes using the ferric peroxo species as an active oxidant. (2) Strongly oxidizing iron (III) complexes as models of the active site intermediates of lipoxygenase. [D] . Wertz, Diana L. 1999

机译：将复合物建模为血红素和非血红素酶机制的探针：（1）使用过氧化铁物种作为活性氧化剂，将过氧化铁卟啉复合物模拟为P450酶。（2）强氧化铁（III）络合物作为脂氧合酶活性位点中间体的模型。
6. Synthesis Photochemical and Photoinduced Antibacterial Activity Studies of meso-Tetra(pyren-1-yl)porphyrin and its Ni Cu and Zn Complexes [O] . Tamara Zoltan, Franklin Vargas, Carlos Rivas, 2010

机译：中四（pyren-1-yl）卟啉及其镍铜和锌配合物的合成光化学和光诱导的抗菌活性研究
7. Single-Boron Complexes of N-Confused and N-Fused Porphyrins [O] . -1

机译：N-混淆和n稠合的卟啉单硼复合物
8. Reaction of Cyclohexene with Iodosylbenzene Catalyzed by Non-Porphyrin Complexesof Iron(III) and Aluminum(III). Newly Discovered Products and a New Mechanistic Proposal [R] . Yang, Y., Diederich, F., Valentine, J. S. 1990

机译：铁（III）和铝（III）非卟啉配合物催化环己烯与碘代苯的反应。新发现的产品和新的机械方案

Ni(III) complex of an N-confused porphyrin inner C-oxide

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