Photothermal Characterization of Nanocomposites Based on High Density Polyethylene (HDPE) Filled with Expanded Graphite

摘要

The effective thermophysical and optical properties of high density polyethylene (HDPE) filled with 50 μm and 5 μm particle sizes of expanded graphite (EG50, EG5) are characterized. The methods used were front- and back-detection modulated photothermal radiometry (FD-, BD-PTR) and BD-flash IR thermography. Results were interpreted according to one-dimensional heat diffusion models. The absolute thermal diffusivity was determined at low frequency from FD- and BD-PTR spectra, while the volumetric heat capacity, the thermal effusivity, and the optical absorption coefficient were determined from broad-band FD-PTR spectra. The directly obtained diffusivity values compare well with those calculated from the heat capacity and thermal effusivity, and with BD-flash results. The errors caused by the finite absorption coefficient of diluted samples are also evaluated and corrected for. A particle-size effect with the opposite influence on thermal and optical properties has been observed. Heat transport parameters of HDPE/EG composites are significantly enhanced (factor of 3 to 4 in thermal diffusivity) at low particle charge before reaching saturation above a 0.10 particle volume fraction. These features are explained in the framework of effective medium models by strongly non-spherical EG particles.