首页> 外国专利> STYRENE-MODIFIED LINEAR LOW-DENSITY POLYETHYLENE-BASED RESIN BEADS, STYRENE-MODIFIED LINEAR LOW-DENSITY POLYETHYLENE-BASED EXPANDABLE RESIN BEADS, PRODUCTION METHOD THEREFOR, PRE-EXPANDED BEADS AND EXPANDED MOLDED ARTICLE

STYRENE-MODIFIED LINEAR LOW-DENSITY POLYETHYLENE-BASED RESIN BEADS, STYRENE-MODIFIED LINEAR LOW-DENSITY POLYETHYLENE-BASED EXPANDABLE RESIN BEADS, PRODUCTION METHOD THEREFOR, PRE-EXPANDED BEADS AND EXPANDED MOLDED ARTICLE

机译:苯乙烯改性的线性低密度聚乙烯基树脂珠,苯乙烯改性的线性低密度聚乙烯基树脂珠,制备方法,预膨胀珠和膨胀模制品

摘要

A method for producing styrene-modified linear low-density polyethylene-based resin particles, which includes the steps of: dispersing 100 parts by weight of non-crosslinked linear low-density polyethylene-based resin particles which are polymerized using a metallocene compound as a catalyst and contain an inorganic nucleating agent, 50 to 800 parts by weight of a styrene-based monomer and 0.1 to 0.9 parts by weight of a polymerization initiator relative to 100 parts by weight of the styrene-based monomer into an aqueous suspension containing a dispersant; impregnating the polyethylene-based resin particles with the styrene-based monomer under heating the resulting dispersion at such a temperature that the styrene-based monomer does not substantially polymerize; and performing polymerization of the styrene-based monomer at a temperature of (T+10) to (T+35)° C. where T° C. is a crystallization peak temperature of the polyethylene-based resin particles.
机译:一种生产苯乙烯改性的线性低密度聚乙烯基树脂颗粒的方法,该方法包括以下步骤:分散100重量份使用茂金属化合物作为原料的非交联的线性低密度聚乙烯基树脂颗粒。相对于100重量份的苯乙烯基单体,在含有分散剂的水性悬浮液中,含有无机成核剂,50〜800重量份的苯乙烯系单体和0.1〜0.9重量份的聚合引发剂。 ;在使所得分散体在苯乙烯基单体基本不聚合的温度下加热所得分散体的同时,将苯乙烯基单体浸渍在聚乙烯基树脂颗粒中。然后在(T + 10)至(T + 35)℃的温度下进行苯乙烯基单体的聚合,其中T℃是聚乙烯基树脂颗粒的结晶峰温度。

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