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Synthesis and properties of polymers containing S-triazine rings in the main chain

机译:主链含S-三嗪环的聚合物的合成与性能

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摘要

Polymers containing s-triazine rings in the main chain were synthesized by interfacial polycondensation reaction of 2,4-dichloro-6-1,1'-hydroxy-1' -naphthyl-s-triazine with various aromatic diols such as bisphenol-A (BPA),bisphenol-s (BPS),and phenolphthalein (PH) using cationic emulsifier (CTMABr) and NaoH as acid acceptor:Polymers were obtained in good yield and were characterized.by solubility,intrinsic viscosity,and FT-IR spectral analysis.The relative solubilities of these polymer samples were determined in a variety of solvents.Thermal stability was studied by TGA technique.
机译:通过2,4-二氯-6-1,1'-羟基-1'-萘基-s-三嗪与各种芳香族二醇如双酚A的界面缩聚反应合成主链上含s-三嗪环的聚合物。以阳离子乳化剂(CTMABr)和NaoH为酸受体的双酚-s(BPS)和酚酞(PH):以良好的收率获得了聚合物,并通过溶解度,固有粘度和FT-IR光谱分析对其进行了表征。测定了这些聚合物样品在各种溶剂中的相对溶解度。通过TGA技术研究了热稳定性。

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