An unusual axial-axial combination of alternating cyclic rings in the chair conformations of hexameric water and chlorine-water clusters

摘要

An alternating hexameric water (H2O)6 cluster and a chlorine-water cluster [C12(H2O)4]~(2+) in the chair forms combine axially to each other to form a ID chain i{CI2(H2C>)6]~(2-)]n in complex [FeL2]Cl-(H2O)3 (L=2-[(2-methylaminoethylimino)-methyl]-phenol)]. The water molecules display extensive H-bonding interactions with monomeric iron-organic units to form a hydrogen-bonded 2D supramolecular assembly.