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Kinetics Studies for the Adsorption of β-Carotene on Mesoporous Carbon Coated Monolith: Effect of Concentration and Temperature

机译:β-胡萝卜素在介孔碳包覆的整料上的吸附动力学:浓度和温度的影响

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摘要

The adsorption kinetics for the removal of β-carotene as functions of temperature and initial P-carotene concentration onto mesoporous j carbon coated monolith in isopropyl alcohol and n-hexane solutions was investigated. The adsorption capacity increased as initial P-carotene concentration and temperature increased. Two kinetic models, pseudo-first-order and pseudo-second-order, were used to describe the adsorption kinetics. To identify the adsorption mechanism rate parameters for intraparticle diffusion model were evaluated. The results showed that the adsorption of β-carotene onto mesoporous carbon coated monolith followed pseudo-first-order model in isopropyl alcohol solution and pseudo-second-order model in n-hexane solution. The activation energies were 11.45 and 9.41 kJ/mol in isopropyl alcohol and n-hexane solutions, respectively.
机译:研究了在异丙醇和正己烷溶液中,β-胡萝卜素的去除动力学随温度和初始P-胡萝卜素的浓度变化而变化的特性,并吸附在介孔碳涂层的整料上。吸附能力随初始β-胡萝卜素浓度和温度的升高而增加。两种动力学模型,伪一级和伪二级被用来描述吸附动力学。为了确定吸附机理,对粒子内扩散模型的速率参数进行了评估。结果表明,β-胡萝卜素在介孔碳包覆的整体柱上的吸附遵循异丙醇溶液中的拟一阶模型和正己烷溶液中的拟二阶模型。在异丙醇和正己烷溶液中的活化能分别为11.45和9.41 kJ / mol。

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