Highly selective fluorogenic anion chemosensors: naked-eye detection of F~- and AcO~- ions in natural water using a test strip

摘要

Two new chemosensors S1 and S2 were synthesized and their chromogenic and fluorogenic behavior towards various biologically important anions in a competing solvent DMSO was investigated. Both the sensors portrayed a substantial color change upon addition of F~- and AcO~- ions and no significant change was observed on addition of other anions such as Cl~-, Br~-, r, ClO4~- and HSO4~-. The binding constant showed that both F~- and AcO~- anions bind to the sensors in an equal proportion, in which S2 was found to be superior and showed a better binding ability than S1. Job's plots indicated that both sensors formed a (1 :1) complex (sensor: anion) with F~- and AcO~- anions. Remarkable fluorescence "turn on" emission behavior was observed with both the sensors when treated with F~- and AcO~-anions respectively. ~1H NMR titration experiments indicated that both S1 and S2 formed a strong hydrogen bond not only with the phenolic-OH but also with the amide-NH of the triazole. We have also demonstrated an easy-to-prepare test strip of S2 to detect F" and AcO" anions even in aqueous medium at a lower limit of about 10 ppm, indicating the potential real-life application of detecting F~- and AcO~- anions in a natural aqueous environment simply through naked-eye observation.