Synthesis of molecularly imprinted dye‐silica nanocomposites with high selectivity and sensitivity: Fluorescent imprinted sensor for rapid and efficient detection of τ‐fluvalinate in vodka

Wang Yunyun; Wang Jixiang; Cheng Rujia; Sun Lin; Dai Xiaohui; Yan Yongsheng

摘要

Abstract > An imprinted fluorescent sensor was fabricated based on SiO <sub>2</sub> nanoparticles encapsulated with a molecularly imprinted polymer containing allyl fluorescein. High fluorine cypermethirin as template molecules, methyl methacrylate as functional monomer, and allyl fluorescein as optical materials synthesized a core‐shell fluorescent molecular imprinted sensor, which showed a high and rapid sensitivity and selectivity for the detection of τ‐fluvalinate. The sensor presented appreciable sensitivity with a limit of 13.251?nM, rapid detection that reached to equilibrium within 3?min, great linear relationship in the relevant concentration range from 0 to 150?nM, and excellent selectivity over structural analogues. In addition, the fluorescent sensor demonstrated desirable regeneration ability (eight cycling operations). The molecularly imprinted polymers ensured specificity, while the fluorescent dyes provided the stabile sensitivity. Finally, an effective application of the sensor was implemented by the detection of τ‐fluvalinate in real samples from vodka. The molecularly imprinted fluorescent sensor showed a promising potential in environmental monitoring and food safety. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</标题> >基于SiO <sub> 2 </ sub>纳米粒子封装的印迹荧光传感器用含烯丙基荧光素的分子印迹聚合物。作为模板分子，甲基丙烯酸甲酯作为功能性单体，以及烯丙基荧光素作为光学材料的高氟氯氰酸甲基丙烯酸酯合成了核 - 壳荧光分子印迹传感器，其显示出对τ-氟盐的检测的高且快速的敏感性和选择性。该传感器呈现了可观的灵敏度，限制为13.251Ω·nm，快速检测到3？min内达到平衡，在相关浓度范围内的巨大线性关系范围为0至150Ω，以及对结构性类似物的优异选择性。此外，荧光传感器展示了所需的再生能力（八个循环操作）。分子印迹聚合物确保特异性，而荧光染料提供了稳定性敏感性。最后，通过检测来自伏特加的真实样品中的τ-氟戊酸盐来实现传感器的有效应用。分子印迹荧光传感器显示出环境监测和食品安全的有希望的潜力。 </ p> </ abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-35800/'>《Journal of separation science.》</a> <b style="margin: 0 2px;">|</b><span>2018年第8期</span><b style="margin: 0 2px;">|</b><span>共8页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Wang Yunyun&option=202" target="_blank" rel="nofollow">Wang Yunyun;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Wang Jixiang&option=202" target="_blank" rel="nofollow">Wang Jixiang;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Cheng Rujia&option=202" target="_blank" rel="nofollow">Cheng Rujia;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Sun Lin&option=202" target="_blank" rel="nofollow">Sun Lin;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Dai Xiaohui&option=202" target="_blank" rel="nofollow">Dai Xiaohui;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Yan Yongsheng&option=202" target="_blank" rel="nofollow">Yan Yongsheng;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>School of Chemistry and Chemical EngineeringJiangsu UniversityZhenjiang P. R. China;</p> <p>School of Chemistry and Chemical EngineeringJiangsu UniversityZhenjiang P. R. China;</p> <p>School of Material Science and EngineeringJiangsu UniversityZhenjiang P. R. China;</p> <p>School of Chemistry and Chemical EngineeringJiangsu UniversityZhenjiang P. R. China;</p> <p>School of Chemistry and Chemical EngineeringJiangsu UniversityZhenjiang P. R. China;</p> <p>School of Chemistry and Chemical EngineeringJiangsu UniversityZhenjiang P. R. China;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/159.html" title="化学">化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=efficient detection&option=203" rel="nofollow">efficient detection;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=fluorescein&option=203" rel="nofollow">fluorescein;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=fluorescent sensor&option=203" rel="nofollow">fluorescent sensor;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=molecular imprinting&option=203" rel="nofollow">molecular imprinting;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=τ‐fluvalinate&option=203" rel="nofollow">τ‐fluvalinate;</a> </p> <div class="translation"> 机译：高效检测;荧光素;荧光传感器;分子印迹;τ-氟盐; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704025846093.html">Synthesis of molecularly imprinted dye‐silica nanocomposites with high selectivity and sensitivity: 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tuijian_authcolor">,谈宜勇</a> <span> <a href="/conference-cn-58918/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 第八届中国化学会分析化学年会暨第八届全国原子光谱学术会议 </a> <span> <span> . 2003</span> </span> </div> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/020314494799.html">谷胱甘肽分子印迹聚合物的合成及应用于荧光传感器膜的研究</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=李琼&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 李琼</a> <span> . 2007</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/06120101694374.html">高选择性多组分的印刷分子印迹纸芯片荧光传感器的研究与现场检测应用</a> <b>[P]</b> . <span> 中国专利： CN103033495A </span> <span> . 2013-04-10</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/06120103420193.html">用于壬基酚检测的石墨烯/聚吡咯纳米复合材料修饰的分子印迹传感器的制备方法及应用</a> <b>[P]</b> . <span> 中国专利： CN110794015A </span> <span> . 2020-02-14</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130427837274.html">NOVEL INSULIN MONITORING DEVICE BASED ON HYPHENATION BETWEEN MOLECULARLY IMPRINTED MICRO-SOLID PHASE EXTRACTION-SILICA-FIBER AND COMPLEMENTARY MOLECULARLY IMPRINTED POLYMER SENSOR TECHNIQUES</a> <b>[P]</b> . <span> 外国专利：  IN2010KO00592A </span> <span> . 2010-08-20</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：基于分子印迹微固相萃取-硅纤维和互补分子印迹聚合物传感器技术加氢的新型胰岛素监测装置 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130403834731.html">Molecularly imprinted polymer with inbuilt redox sampler and salt that provides counterions and the selective chemical sensor for electrochemical marking of selected analytes with a layer of the molecularly imprinted polymer as the recognizing unit</a> <b>[P]</b> . <span> 外国专利：  PL422855A1 </span> <span> . 2019-03-25</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：具有内置氧化还原采样器和盐的分子印迹聚合物，该盐提供抗衡离子和选择性化学传感器，用于以分子印迹聚合物层作为识别单元对选定的分析物进行电化学标记 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130412272080.html">Templates of aflatoxin, Methods Of Synthesis of a compound of aflatoxin POLIMu00c9RICO intermediary template, molecularly imprinted polymer, method of preparation of molecularly imprinted molecularly imprinted Polymers, and Methods of secuestraciu00d3n of aflatoxin</a> <b>[P]</b> . <span> 外国专利：  AR099241A1 </span> <span> . 2016-07-06</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：黄曲霉毒素的模板，黄曲霉毒素POLIM u00c9RICO中间体模板的化合物的合成方法，分子印迹聚合物，分子印迹分子印迹聚合物的制备方法以及黄曲霉毒素的secuestraci u00d3n方法 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 class="all_title" id="enpatent55">相关主题</h3> <ul id="subject"> </ul> </div> </div> </div> </div> <div class="right rightcon"> <div class="details_img cardcommon clearfix" style="margin-bottom: 10px;display:none;" > </div> </div> </div> <div id="thesis_get_original1" class="downloadBth" style="bottom: 19px;z-index: 999;" onclick="ywcd('0704025846093','4',7,2,1,'',this,24)" class="delivery" prompt="010401" title="通过人工服务将文献原文发送至邮箱" >获取原文</div> <div class="journalsub-pop-up" style="display: none"> <div class="journal-sub"> <h2>期刊订阅</h2> <img src="https://cdn.zhangqiaokeyan.com/img/loginclose.png" alt="关闭" onclick="$('.journalsub-pop-up').hide()"> <p class="pardon">抱歉，该期刊暂不可订阅，敬请期待！</p> <p class="current">目前支持订阅全部北京大学中文核心（2020）期刊目录。</p> <div style="display: flex;margin-top: 69px;justify-content: 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