High-resolution FTIR spectroscopic study of (GeH4)-Ge-73 up to 2300 cm(-1)

摘要

The spectra of germane enriched up to 99.9 % of (GeH4)-Ge-73 were recorded with a high resolution (0.003 cm(-1)) at different pressures with the Bruker IFS 125HR Fourier transform spectrometer (Nizhny Novgorod, Russia) in the region of 650-4400 cm(-1) and analyzed in the Dyad and Pentad region. The 9208 transitions belonging to the seven "cold" bands (6987 transitions) of the Dyad and Pentad and to the nine "hot" Dyad-Pentad bands (2221 transitions) were assigned and theoretically analysed in the frame of the effective Hamiltonian model. The obtained set of 68 fitted parameters reproduces the initial 9208 experimental line positions with the d(rms) = 2.82 x 10(-4) cm(-1). (C) 2018 Elsevier Ltd. All rights reserved.