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首页> 外文期刊>Journal of Physical Organic Chemistry >Olefinic vs aromatic way of substituent effects: The case of 3‐ and 4‐substituted cyclohexa‐1,3‐dienamine derivatives
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Olefinic vs aromatic way of substituent effects: The case of 3‐ and 4‐substituted cyclohexa‐1,3‐dienamine derivatives

机译：烯烃与取代基的芳香方式：3-和4取代的环己酰胺-1,3-二烯胺衍生物的情况

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Abstract > Quantum chemical modeling was used to confront substituent effects in olefinic systems with an analogous situation in benzene. The B3LYP/6‐311++G(d,p) method was applied to examine electron‐donating properties of the amino group in a series of 3‐ (meta‐like) and 4‐ (para‐like) X‐substituted cyclohexa‐1,3‐dienamines (X?=?NMe <sub>2</sub> , NH <sub>2</sub> , OH, OMe, Me, H, F, Cl, CF <sub>3</sub> , CN, CHO, COMe, CONH <sub>2</sub> , COOH, NO <sub>2</sub> , NO). As in the case of substituted anilines (PCCP, 2016, 18, 11711), the substituent properties were described by σ, charge of the substituent active region(X), and substituent effect stabilization energy descriptors; the amino group was characterized by structural and electronic parameters, whereas a transmitting moiety—by aromaticity index harmonic oscillator model of aromaticity. All applied substituent properties parameters were found to be mutually interrelated, with much better correlations for the para‐derivatives than the meta‐derivatives. Electron‐donating ability of the amino group is stronger affected (circa 1.4 times) by substituent acting from position 4 in cyclohexa‐1,3‐dienamines than in aniline derivatives. It was also numerically confirmed that the reverse substituent effect acting to para‐position is stronger (circa 1.14 times) in olefinic systems than in aromatic ones. Moreover, for 1‐4 interactions, an increase of the electron‐attracting power of the substituent increases π‐electron delocalization in the olefinic series, whereas decreases it in the aromatic ones. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>摘要</标题> >量子化学模型用于在苯中具有类似局面的烯烃体系中的取代基效果。施用B3Lyp / 6-311 ++ g（d，p）方法以检查氨基中的一系列3-（meta样）和4-（para样）X取代的环己蛋白-1,3-二烯胺（x？=Δnme<sub> 2 </ sub>，nh <sub> 2 </ sub>，oh，Ome，me，h，f，cl，cf <sub> 3 </ Sub>，CN，CHO，到来，CONH <SUB> 2 </ SUB>，COOH，NO <SUB> 2 </ SUB>，NO）。与取代的苯胺（PCCP，2016,18,11711）一样，取代基通过σ，取代基有源区（X）的电荷，以及取代基效应稳定能量描述符。氨基的特征在于结构和电子参数，而通过芳香性指数谐振振荡器模型的传播部分。发现所有应用的取代基特性参数相互相互相互关联，比荟萃衍生物具有更好的相关性。氨基的电子赋予氨基的能力较强受影响的较强（大约1.4次），取代基于苯胺衍生物在环己-1,3-丁胺中的位置4中取代。在数值上证实，作用于对位置的反向取代基效应比在芳族体系中更强（大约1.14倍）。此外，对于1-4个相互作用，取代基的吸电子功率的增加会增加烯烃系列中的π电子临床化，而在芳族系列中将其降低。 </ p> </ abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-35546/'>《Journal of Physical Organic Chemistry》</a> <b style="margin: 0 2px;">|</b><span>2017年第12期</span><b style="margin: 0 2px;">|</b><span>共9页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Szatylowicz Halina&option=202" target="_blank" rel="nofollow">Szatylowicz Halina;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Siodla Tomasz&option=202" target="_blank" rel="nofollow">Siodla Tomasz;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Krygowski Tadeusz M.&option=202" target="_blank" rel="nofollow">Krygowski Tadeusz M.;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Faculty of ChemistryWarsaw University of TechnologyNoakowskiego 3 00‐664 Warsaw Poland;</p> <p>Faculty of ChemistryAdam Mickiewicz UniversityUmultowska 89b 61‐614 Poznań Poland;</p> <p>Department of ChemistryWarsaw UniversityPasteura 1 02‐093 Warsaw Poland;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/4796.html" title="有机化学一般性问题">有机化学一般性问题;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=aniline derivatives&option=203" rel="nofollow">aniline derivatives;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=aromaticity&option=203" rel="nofollow">aromaticity;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=cyclohexadiene derivatives&option=203" rel="nofollow">cyclohexadiene derivatives;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=substituent effect&option=203" rel="nofollow">substituent effect;</a> </p> <div class="translation"> 机译：苯胺衍生物;芳香性;环己二烯衍生物;取代基效应; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704025793840.html">Olefinic vs aromatic way of substituent effects: The case of 3‐ and 4‐substituted cyclohexa‐1,3‐dienamine derivatives</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Szatylowicz Halina&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Szatylowicz Halina,</a> <a 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K.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Dad, K. K. </a> <span>1998</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：5-取代-1,3-二氮杂环庚烷衍生物的合成与表征</span> </p> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/academic-journal-cn_chinese-journal-synthetic-chemistry_thesis/0201234498707.html">多取代芳香族化合物的合成4.取代的环丁-3-烯砜与丁炔二酸二甲酯的Diels-Alder反应</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=韩广甸&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 韩广甸</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=黄国锋&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,黄国锋</a> <span> <a href="/journal-cn-11569/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 合成化学 </a> </span> <span> . 1997</span><span>,第001期</span> </span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/academic-journal-cn_chemical-journal-chinese-universities_thesis/0201231660778.html">(Z)-1，2-二苯基-1，3-丁二烯与单取代的乙烯衍生物区位选择性环加成反应</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=谢周&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 谢周</a> <span> <a href="/journal-cn-10958/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 高等学校化学学报 </a> </span> <span> . 1990</span><span>,第004期</span> </span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/academic-journal-cn_chinese-journal-organic-chemistry_thesis/0201295140997.html">无外加催化剂条件下邻取代芳香醛与5,5-二甲基-1,3-环己二酮的反应研究</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=王苏惠&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 王苏惠</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=史达清&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,史达清</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=屠树江&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,屠树江</a> <span> <a href="/journal-cn-15847/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 有机化学 </a> </span> <span> . 1999</span><span>,第5期</span> </span> </div> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/academic-journal-cn_detail_thesis/0201297751145.html">新型七氟异丙基取代2,2-二氟-1,3-苯并二氧-5-乙酰胺衍生物的合成与杀虫活性（英文）</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=刘杰&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 刘杰</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=朱冰春&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,朱冰春</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=裴丹&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,裴丹</a> <span> <a href="/journal-cn-56778/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 农药学学报 </a> </span> <span> . 2019</span><span>,第1期</span> </span> </div> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/academic-journal-cn_chinese-journal-organic-chemistry_thesis/0201292967531.html">2,2-亚戊基-1,3-二氧六环-4,6-二酮与原甲酸三乙酯和芳香胺的反应</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=徐福培&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 徐福培</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=丁维钰&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,丁维钰</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=笪宝林&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,笪宝林</a> <span> <a href="/journal-cn-15847/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 有机化学 </a> </span> <span> . 1991</span><span>,第3期</span> </span> </div> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-conference-cn_meeting-31988_thesis/02022485395.html">7β-杂环酰胺基-3-(2-取代1,3,4-恶二唑-5-硫亚甲基)头孢菌素衍生物半合成及抗菌活性研究</a> <b>[C]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=惠新平&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 惠新平</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=和艳&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,和艳</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=许鹏飞&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,许鹏飞</a> <span> <a href="/conference-cn-31988/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 第八届全国有机合成学术会议 </a> <span> <span> . 2000</span> </span> </div> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" 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