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Factors affecting the separation performance of graphene oxide membranes: mechanical support, properties of graphene oxide, and exotic species

机译:影响石墨烯膜分离性能的因素:机械载体,石墨烯的性质和异国情调的物种

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Abstract <section xml:id="jctb5505-sec-0001" numbered="no"> <title type="main">BACKGROUND >Graphene oxide (GO) membrane with 2‐dimensional nanocapillaries has gained worldwide attention. To manipulate the membrane separation performance, most existing studies focused on sandwiching appropriate species between GO layers. This study aimed to provide multiple strategies to manipulate the GO membrane separation performance, including the mechanical support, properties of GO nanosheets, and exotic species (i.e. cross‐linkers and residual water molecules). </section> <section xml:id="jctb5505-sec-0002" numbered="no"> <title type="main">RESULTS > Used as the support material, compared with the nitrocellulose membrane, the polyvinylidene fluoride membrane offered stronger mechanical strength to ensure a stable flux. Additional mechanical support could be provided by the non‐woven cloth underneath the GO membrane. The use of GO nanosheets with smaller sizes obtained by centrifugation of the GO suspension increased the water flux and NaCl rejection. Cross‐linking GO layers by Ca 2+ resulted in a decreased water flux but increased salt rejection. The same phenomena was observed for the GO membranes post‐treated by vacuum drying, which, compared with air drying, evaporated more residual water molecules from the nanocapillaries. </section> <section xml:id="jctb5505-sec-0003" numbered="no"> <title type="main">CONCLUSION >Results suggested that the mechanical support, properties of GO nanosheets, cross‐linkers, and residual water molecules greatly affected the membrane water flux and rejections, which could be utilized as strategies to manipulate the GO membrane separation performan </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译:</span><Abstract XMLNS =“http://www.wiley.com/namespaces/wiley”type =“main”xml:lang =“en”> <title type =“main”>抽象</ title> <section XML:ID =“JCTB5505-SEC-0001”编号=“否”> <标题类型=“MAIN”>背景</标题> >具有二维纳米粉的石墨烯氧化物(GO)膜在全球范围内。为了操纵膜分离性能,大多数现有的研究都集中在GO层之间夹着适当的物种。本研究旨在提供多种策略来操纵去膜分离性能,包括机械支撑,Go纳米片的性质和异国情调(即交联剂和残留水分子)。</ p> </段> <截面XML :ID =“JCTB5505-SEC-0002”编号=“否”> <标题类型=“主要”>结果</标题> <P>与硝酸纤维素膜相比,聚偏二氟醚膜相比较强机械强度以确保稳定的通量。可以通过去膜下方的无纺布提供额外的机械支撑。通过离心去悬浮液获得的较小尺寸的使用纳米片增加了水通量和NaCl排斥。 CA <SUP> 2 + </ sup>交联去层导致水通量减少,但盐排斥增加。对于通过真空干燥后处理的去膜观察到相同的现象,与空气干燥相比,从空气干燥相比,蒸发从纳米粉的更残余的水分子。 </ p> </ section> <部分XML:ID =“JCTB5505-SEC-0003”编号=“否”> <标题类型=“main”>结论</ title> >结果表明机械支持, Go Nanosheets,交联剂和残留水分子的性质极大地影响了膜水通量和拒绝,可以用作操纵Go膜分离性能的策略 </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-33908/'>《Journal of Chemical Technology & Biotechnology》</a> <b style="margin: 0 2px;">|</b><span>2018年第5期</span><b style="margin: 0 2px;">|</b><span>共6页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Mo Yinghui&option=202" target="_blank" rel="nofollow">Mo Yinghui;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zhao Xin&option=202" target="_blank" rel="nofollow">Zhao Xin;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Yuan Tingting&option=202" target="_blank" rel="nofollow">Yuan Tingting;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=He Benqiao&option=202" target="_blank" rel="nofollow">He Benqiao;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>State Key Laboratory of Separation Membranes and Membrane ProcessesSchool of Environmental and Chemical Engineering Tianjin Polytechnic UniversityTianjin China;</p> <p>School of Environmental Science and EngineeringTianjin UniversityTianjin China;</p> <p>School of Material Science and EngineeringTianjin Polytechnic UniversityTianjin China;</p> <p>School of Material Science and EngineeringTianjin Polytechnic UniversityTianjin China;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/180.html" title="生物工程学(生物技术)">生物工程学(生物技术);</a><a href="https://www.zhangqiaokeyan.com/clc/20827.html" title="生物化学过程">生物化学过程;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=graphene oxide membrane&option=203" rel="nofollow">graphene oxide membrane;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=separation performance&option=203" rel="nofollow">separation performance;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=mechanical support&option=203" rel="nofollow">mechanical support;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=size&option=203" rel="nofollow">size;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=cross‐linkers&option=203" rel="nofollow">cross‐linkers;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=residual water&option=203" rel="nofollow">residual water;</a> </p> <div class="translation"> 机译:石墨烯氧化物膜;分离性能;机械支撑;尺寸;交联剂;残留的水; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704025422850.html">Factors affecting the separation performance of graphene oxide membranes: mechanical support, properties of graphene oxide, and exotic species</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Mo Yinghui&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Mo Yinghui,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zhao 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