Comparative study on front emitter and rear emitter n-type silicon heterojunction solar cells: The role of folded electrical fields

摘要

Here, we presented a comparative investigation on the front and rear emitter n-type silicon heterojunction (SHJ) solar cells. The cell performances showed that the rear emitter SHJ solar cell featured higher open-circuit voltage (V-oc), fill factor (FF) and conversion efficiency (Eff.), but suffering from a lower short-circuit current density (J(sc)). The poor J(sc) agreed well with the external quantum efficiency (EQE) results, that rear emitter SHJ had a inferior EQE than the front emitter ones, although the thinner a-Si:H(n(+)) layer had a better optical transmittance than that of a-Si:H(p) layer. Then, by adjusting the thickness of two sides intrinsic hydrogenated amorphous silicon (a-Si:H(i)) layers in the rear emitter SHJ solar cells, the Ells were further improved. It was believed that the folded electrical fields formed by ITO, doped a-Si:H layers, and n-type crystalline silicon (c-Si(n)) substrate played a great role on the cell performances. Consequently, by combining the optimized thickness of doped and intrinsic a-Si:H layers, for the rear emitter SHJ solar cells, a full-area certified Eff of 21.71% on large area of 238.9 cm(2) substrate was obtained, with a V-oc of 0.731 V, J(sc) of 37.46 mA/cm(2), and FF of 0.793. Note that, the 21.71% full-area conversion efficiency relates to an aperture-area conversion efficiency of 22.57%. (C) 2017 Elsevier Ltd. All rights reserved.