Preparation and characterization of polyphenylene sulfide/graphene nanoplatelets composite fibers with enhanced oxidation resistance

摘要

Composite masterbatches of polyphenylene sulfide (PPS) with functionalized graphene nanoplatelets (GNPs) were prepared by melt blending via a twin-screw extruder. The structure and morphology of composite masterbatches were characterized by scanning electron microscopy and X-ray diffraction analysis. The PPS/functionalized GNPs composite fibers were then manufactured by a self-made spinning equipment via melt spinning. The oxidation resistance and other properties of PPS composite fibers were also examined. The results showed that the pure PPS fibers exhibited smooth surface, whereas the surface of PPS/functionalized GNPs composite fibers was rough. The addition of functionalized GNPs could be acted as heterogeneous nucleating agents to improve the crystallization and increase the degree of crystallinity. The retention rate of breaking strength of PPS/functionalized GNPs composite fibers could maintain up to 85% after the oxidation treatment. The improvement in the oxidation resistance of PPS/functionalized GNPs composite fibers is the results of comprehensive effects characterized by the X-ray photoelectron spectroscopy analyses. The addition of functionalized GNPs could limit the damage of the C-S group and retard the generation of sulfuryl groups (-SO-) during the oxidation treatment. The chemical combination of the elements sulfur (S) and oxygen (O) could also be restricted, thus weakening the oxidation activity.