2(PO 4) 3 composite: A promising anode material for sodium-ion batteries with superior Na-storage performance]]>

摘要

AbstractNASICON-type NaTi2(PO4)3material has been extensively studied as a promising anode for sodium-ion batteries due to the open 3D framework with the large interstitial spaces, high theoretical capacity and small volume change during cycling process. However, the practical application of NaTi2(PO4)3is hampered because of its low electronic conductivity. Herein, a simple approach along with post-annealing has been designed and adopted to prepare the carbon-coated NaTi2(PO4)3(NaTi2(PO4)3@C) composite. The as-prepared anode material is characterized by XRD, SEM, TEM and Raman spectrum. The electrochemical measurements reveal that NaTi2(PO4)3@C has excellent Na-storage performances including high reversible capacity (112.6mAhg?1at 0.2C) and good rate capability (87.1mAhg?1at 5C). The superior electrochemical performance can be resulted from the synergistic effects of the nanosized NaTi2(PO4)3particles and conductive carbon layer.