On the mechanism of cobalt(III) aminates pyrolysis

摘要

Pyrolysis of the complex (ato-N-2)pentaammincobalt(III) perchlorate and the ligand 5-nitrotetrazole, and also of the initial complex aquapentaammincobalt(III) perchlorate was studied by the mass spectroscopy method. The leading oxidizer of ligands in the complexes is changed for the outer-sphere perchlorate ion at the pyrolysis temperature of similar to 250A degrees C.