The mechanisms of tris(4-morpholinecarbodithioato-S, S') co- balt(III) complex formation by solid state reaction from ammine cobalt(III) complexes

摘要

In this paper, the solid state reaction, conducted with a mixture of pentaam- minechlorocobalt (III) chloride and potassium 4-morpholinecarbodithioate was investi- gated under isothermal conditions. The reaction proceeds at relatively low temperatures (154-192 deg. C). The yield of product solid-solid reaction, tris (4-morpholinecarbodithio- ato-S, S') cobalt (III) complex, does not exceed 65/100. The kinetic of the reaction of powdered and pressed samples were investigated. The reaction proceeded according to the diffusional mechanism.