Rapid, controllable, one‐pot and room‐temperature aqueous synthesis of ZnO:Cu nanoparticles by pulsed UV laser and its application for photocatalytic degradation of methyl orange

Arabi Mozhgan; Baizaee Seyyed Mahdy; Bahador Alireza; Otaqsara Seyed Mohammad Taheri

摘要

Abstract > Zinc oxide (ZnO) and ZnO:Cu nanoparticles (NPs) were synthesized using a rapid, controllable, one‐pot and room‐temperature pulsed UV‐laser assisted method. UV‐laser irradiation was used as an effective energy source in order to gain better control over the NPs size and morphology in aqueous media. Parameters effective in laser assisted synthesis of NPs such as irradiation time and laser shot repetition rate were optimized. Photoluminescence (PL) spectra of ZnO NPs showed a broad emission with two trap state peaks located at 442 and 485?nm related to electronic transition from zinc interstitial level (I <sub>Zn</sub> ) to zinc vacancy level (V <sub>Zn</sub> ) and electronic transition from conduction band to the oxygen vacancy level (V <sub>O</sub> ), respectively. For ZnO:Cu NPs, trap state emissions disappeared completely and a copper (Cu)‐related emission appeared. PL intensity of Cu‐related emission increased with the increase in concentration of Cu 2+ , so that for molar ratio of Cu:Zn 2%, optimal value of PL intensity was obtained. The photocatalytic activity of Cu‐doped ZnO revealed 50 and 100% increasement than that of undoped NPs under UV and visible irradiation, respectively. The enhanced photocatalytic activity could be attributed to smaller crystal size, as well as creation of impurity acceptor levels (T <sub>2</sub> ) inside the ZnO energy band gap. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</标题> >氧化锌（ZnO）和ZnO：Cu纳米颗粒（NPS）使用快速合成，可控，单锅和室温脉冲UV激光辅助方法。 UV激光照射用作有效的能量源，以便在水性介质中更好地控制NPS尺寸和形态。优化了激光辅助合成NPS的参数，例如照射时间和激光射击重复率。 ZnO NPS的光致发光（PL）谱显示出具有位于442和485Ω·NM的宽发射，其与从锌间质水平（I <sub> Zn </ sub>）到锌空位水平的电子转换（V <亚> Zn </ sub>）和从导通带到氧空位水平的电子转换（V <sub> o </ sub>）。对于ZnO：Cu NPS，陷阱状态排放完全消失，出现了铜（Cu）复合排放。 Cu相关发射的Pl强度随着Cu 2 + / sup>浓度的增加而增加，使得对于Cu：Zn 2％的摩尔比，得到Pl强度的最佳值。 Cu掺杂ZnO的光催化活性显露于UV和可见辐射下未掺杂的NPS的50％和100％。增强的光催化活性可归因于较小的晶体尺寸，以及ZnO能带隙中的杂质受体水平（T <SUB> 2 </ sub>）。 </ p> </ abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" > 著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-26441/'>《Luminescence: The journal of biological and chemical luminescence 》</a> <b style="margin: 0 2px;">|</b><span>2018年第3期</span><b style="margin: 0 2px;">|</b> <span>共11页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Arabi Mozhgan&option=202" target="_blank" rel="nofollow">Arabi Mozhgan;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Baizaee Seyyed Mahdy&option=202" target="_blank" rel="nofollow">Baizaee Seyyed Mahdy;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Bahador Alireza&option=202" target="_blank" rel="nofollow">Bahador Alireza;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Otaqsara Seyed Mohammad Taheri&option=202" target="_blank" rel="nofollow">Otaqsara Seyed Mohammad Taheri;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Department of Physics Faculty of ScienceVali‐e‐Asr UniversityRafsanjan Iran;</p> <p>Department of Physics Faculty of ScienceVali‐e‐Asr UniversityRafsanjan Iran;</p> <p>Department of Physics Faculty of ScienceVali‐e‐Asr UniversityRafsanjan Iran;</p> <p>Department of PhysicsShahed UniversityTehran Iran;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li> <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span> <a href="https://www.zhangqiaokeyan.com/clc/1345.html" title="生物光学">生物光学 ;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=excimer laser&option=203" rel="nofollow">excimer laser;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=methyl orange&option=203" rel="nofollow">methyl orange;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=photocatalytic activity&option=203" rel="nofollow">photocatalytic activity;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=ZnO&option=203" rel="nofollow">ZnO;</a> </p> <div class="translation"> 机译：准分子激光;甲基橙;光催化活性;ZnO; 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张丽</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=陈浩&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,陈浩</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=黄春艳&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,黄春艳</a> <span> <a href="/journal-cn-4530/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 湖南理工学院学报（自然科学版） </a> </span> <span> . 2010</span><span> ,第004期</span> </span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/academic-journal-cn_detail_thesis/0201293497667.html">PI/ZnO-UV/类Fenton光催化降解甲基橙废水</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=王晓丹&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 王晓丹</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=雷永林&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,雷永林</a> <a 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