Water‐Soluble Binders for Lithium‐Ion Battery Graphite Electrodes: Slurry Rheology, Coating Adhesion, and Electrochemical Performance

Jeschull Fabian; Brandell Daniel; Wohlfahrt‐Mehrens Margret; Memm Michaela

摘要

Abstract >Water‐processable composite electrodes are attractive both ecologically and economically. The binders sodium carboxymethyl cellulose (CMC‐Na) and poly(sodium acrylate) (PAA‐Na) were shown to have improved electrochemical performance over conventional binders. In many studies, a binder content of approximately 10?wt?% has been applied, which is not suitable for large‐scale electrode production due to viscosity and energy‐density considerations. Therefore, we examined herein three electrode formulations with binder contents of 4?wt?%, namely, CMC‐Na:SBR (SBR=styrene butadiene rubber), PAA‐Na, and CMC‐Na:PAA‐Na, on both laboratory and pilot scales. The formulations were evaluated on the basis of slurry rheology, coating adhesion, and electrochemical behavior in half‐ and full‐cells. CMC‐Na:SBR composites provided the best coating adhesion, independent of the mass loading and scale, and also showed the best capacity retention after 100?cycles. Previously reported merits of better cycling efficiencies and solid–electrolyte interphase formation for graphite–PAA composites appeared to vanish upon reducing the binder content to realistic levels. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><abstract xmlns =“http://www.wiley.com/namespaces/wiley”type =“main”xml：lang =“en”> <title type =“main”>抽象</ title> >水 - 可加工的复合电极在生态和经济上具有吸引力。显示粘合剂羧甲基纤维素（CMC-NA）和聚（丙烯酸钠）（PAA-NA），在常规粘合剂上具有改善的电化学性能。在许多研究中，已经施加了大约10〜wt？％的粘合剂含量，这是由于粘度和能量密度考虑因素而不适合大型电极生产。因此，我们在本文中检查了三个电极配方，其中粘合剂含量为4〜wt？％，即CMC-NA：SBR（SBR =苯乙烯丁二烯橡胶），Paa-Na和CMC-Na：Paa-Na，在实验室和飞行员标度。在半和全细胞中的浆料流变学，涂层粘附和电化学行为的基础上评价制剂。 CMC-NA：SBR复合材料提供了最佳的涂层粘附，与大量载荷和刻度无关，并且还显示100℃后的最佳容量保留。以前报道了石墨 - PAA复合材料的更好循环效率和固体电解质相互相互作用的优点似乎在将粘合剂含量降低到现实水平时消失。</ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-22585/'>《Energy Technology: Generation,Conversion,Storage,Distribution》</a> <b style="margin: 0 2px;">|</b><span>2017年第11期</span><b style="margin: 0 2px;">|</b><span>共11页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Jeschull Fabian&option=202" target="_blank" rel="nofollow">Jeschull Fabian;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Brandell Daniel&option=202" target="_blank" rel="nofollow">Brandell Daniel;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Wohlfahrt‐Mehrens Margret&option=202" target="_blank" rel="nofollow">Wohlfahrt‐Mehrens Margret;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Memm Michaela&option=202" target="_blank" rel="nofollow">Memm Michaela;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Department of Chemistry—?ngstr?m LaboratoryUppsala UniversityBox 538 75121 Uppsala Sweden;</p> <p>Department of Chemistry—?ngstr?m LaboratoryUppsala UniversityBox 538 75121 Uppsala Sweden;</p> <p>Accumulators Materials ResearchCenter for Solar Energy and Hydrogen ResearchLise-Meitner-Stra?e 24 89081 Ulm Germany) Fax: (+49)?(0)7319530599;</p> <p>Accumulators Materials ResearchCenter for Solar Energy and Hydrogen ResearchLise-Meitner-Stra?e 24 89081 Ulm Germany) Fax: (+49)?(0)7319530599;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/233.html" title="能源与动力工程">能源与动力工程;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=binders&option=203" rel="nofollow">binders;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=electrochemistry&option=203" rel="nofollow">electrochemistry;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=energy conversion&option=203" rel="nofollow">energy conversion;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=graphite&option=203" rel="nofollow">graphite;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=lithium-ion batteries&option=203" rel="nofollow">lithium-ion batteries;</a> </p> <div class="translation"> 机译：粘合剂;电化学;能量转换;石墨;锂离子电池; 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href="/academic-conference-cn_meeting-41419_thesis/020222470423.html">大肠杆菌粘附涂层固定相用于开管毛细管电色谱手性分离</a> <b>[C]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=付琦峰&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 付琦峰</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=高蝶&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,高蝶</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=王路军&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,王路军</a> <span> <a href="/conference-cn-41419/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 第21届全国色谱学术报告会 </a> <span> <span> . -1</span> </span> </div> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/020315784107.html">汉麻秸秆基生物质碳用于锂离子电池负极及其电化学性能研究</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=关中相&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 关中相</a> <span> . 2020</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/061201607230.html">用于水溶性内衬材料的水溶性粘附剂涂层</a> <b>[P]</b> . <span> 中国专利： CN102575417B </span> <span> . 2015.04.08</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/06120106769507.html">用于水溶性内衬材料的水溶性粘附剂涂层</a> <b>[P]</b> . <span> 中国专利： CN102575417A </span> <span> . 2012-07-11</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130405028280.html">SLURRY FOR SECONDARY BATTERY NEGATIVE ELECTRODE, SECONDARY BATTERY ELECTRODE, SECONDARY BATTERY, PRODUCTION METHOD OF SECONDARY BATTERY ELECTRODE, AND USE OF WATER-SOLUBLE BINDER AS SLURRY FOR SECONDARY BATTERY NEGATIVE ELECTRODE</a> <b>[P]</b> . <span> 外国专利：  JP2018181700A </span> <span> . 2018-11-15</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：二次电池负极的浆料，二次电池电极，二次电池，二次电池的生产方法以及水溶性粘合剂作为二次电池负极的浆料 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130410427050.html">Water-soluble binder composition for secondary battery, mixture for secondary battery electrode, electrode for secondary battery, lithium ion secondary battery</a> <b>[P]</b> . <span> 外国专利：  JP6145638B2 </span> <span> . 2017-06-14</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：二次电池用水溶性粘合剂组合物，二次电池电极用混合物，二次电池电极，锂离子二次电池 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130439392504.html">NEGATIVE ELECTRODE COMPOSITION COMPRISING SYNTHETIC RUBBER-BASED BINDER, CELLULOSE-BASED DISPERSANT AND WATER-SOLUBLE ANIONIC POLYELECTROLYTE, AND NEGATIVE ELECTRODE AND LITHIUM BATTERY USING THE SAME</a> <b>[P]</b> . <span> 外国专利：  KR20040110665A </span> <span> . 2004-12-31</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：包含合成橡胶基粘合剂，纤维素基分散剂和水溶性阴离子聚合物，以及负电极和锂电池的负电极组合物 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 class="all_title" id="enpatent55">相关主题</h3> <ul id="subject"> </ul> </div> </div> </div> </div> <div class="right rightcon"> <div class="details_img cardcommon clearfix" style="margin-bottom: 10px;display:none;" > </div> </div> </div> <div id="thesis_get_original1" class="downloadBth" style="bottom: 19px;z-index: 999;" onclick="ywcd('0704023183682','4',7,2,1,'',this,24)" class="delivery" prompt="010401" title="通过人工服务将文献原文发送至邮箱" >获取原文</div> <div class="journalsub-pop-up" style="display: none"> <div class="journal-sub"> 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