Magnetic deep eutectic solvent-based ultrasoundassisted liquid-liquid microextraction for determination of hexanal and heptanal in edible oils followed by gas chromatography-flame ionization detection

摘要

Use of a novel magnetic deep eutectic solvent (MDES), consisting of the inexpensive and simple components [choline chloride/para-cresol] [FeCl4] was examined using ultrasound-assisted liquid-liquid microextraction and back-extraction methods to determine hexanal and heptanal in edible oils. The MDES was specified using vibrating sample magnetometry (VSM), proton nuclear magnetic resonance (H-1-NMR), CHN elemental analysis, as well as Raman and Fourier-transform-infrared (FT-IR) spectroscopy. Effective factors, including the volume of back-extraction solvent (L), MDES (L) volume, as well as extraction and back-extraction times (min) were optimized through a Box-Behnken design. Under optimal conditions, the calibration graphs of both analytes were linear at 0.05-100 mg L-1, with correlation coefficients 0.999. The limit of detection and limit of quantification was 19-25 g L-1 and 63-83 g L-1, respectively. This method was used to determine target analytes in spiked samples of edible oils; the relative mean recovery ranged from 94% to 102%.