Deposition Dependent Ion Transport in Doped Conjugated Polymer Films: Insights for Creating High‐Performance Electrochemical Devices

Zhang Lushuai; Andrew Trisha L.

摘要

Abstract > Charge conduction and redox events in films of doped conjugated polymers are necessarily accompanied by counterion transport. However, insights into how deposition conditions affect ion transport in a structurally diverse set of doped conjugated polymer films and across a polymer/electrolyte interface have not been gathered. Here, cyclic voltammetry and electrogravimetry measurements are used to probe solvent and ion transport across a doped conjugated polymer/electrolyte interface. A representative polymer, p ‐doped poly(3,4‐ethlyenedioxythiophene) (PEDOT), obtained using two different deposition methods, vapor phase polymerization (VPP) and oxidative chemical vapor deposition (oCVD), is studied. PEDOT films obtained via VPP and oCVD display dissimilar morphologies at the micro‐ and nanometer length scales, resulting in significantly differing swelling behavior, mass trapping, and ion transport upon exposure to a periodic applied potential. PEDOT films obtained using oCVD display notable permselectivity and near‐ideal mass transport during repeated doping/dedoping cycles in various electrolytes, indicating that these films are robust electroactive materials. This study underlines the extent to which film deposition conditions affect ion transport across polymer/electrolyte interfaces and provides insights into optimal film forming conditions for high‐performance supercapacitors and electrochemical transistors. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> > 掺杂共轭聚合物薄膜中的电荷传导和氧化还原事件必然伴有抗衡离子运输。然而，沉积条件如何影响在结构各种掺杂的掺杂掺杂的共轭聚合物膜中的离子输送和横跨聚合物/电解质界面的见解。这里，循环伏安法和电抛光测量测量用于探测溶剂和离子传输，穿过掺杂的共轭聚合物/电解质界面。代表性聚合物， p </ i> - 研究了使用两种不同的沉积方法，蒸汽相聚合（VPP）和氧化化学气相沉积（OCVD）获得的聚（3,4-乙基苯二甲酸噻吩）（PEDOT）。通过VPP和OCVD获得的佩特膜在微型和纳米长度尺度上显示不同的形态，导致暴露于周期性施加电位时显着不同的膨胀行为，质量捕获和离子输送。使用OCVD显示器获得的佩特膜在各种电解质中的重复掺杂/缩小循环期间获得的OCVD显示出显着的渗滤性和接近理想的质量传输，表明这些薄膜是坚固的电活性材料。该研究强调了膜沉积条件影响聚合物/电解质接口的离子输送的程度，并为高性能超级电容器和电化学晶体管提供最佳成膜条件的见解。 </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-18063/'>《Advanced materials interfaces》</a> <b style="margin: 0 2px;">|</b><span>2017年第23期</span><b style="margin: 0 2px;">|</b><span>共9页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zhang Lushuai&option=202" target="_blank" rel="nofollow">Zhang Lushuai;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Andrew Trisha L.&option=202" target="_blank" rel="nofollow">Andrew Trisha L.;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Departments of Chemistry and Chemical EngineeringUniversity of Massachusetts AmherstAmherst MA 01003 USA;</p> <p>Departments of Chemistry and Chemical EngineeringUniversity of Massachusetts AmherstAmherst MA 01003 USA;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/6960.html" title="特种结构材料">特种结构材料;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=conducting polymers&option=203" rel="nofollow">conducting polymers;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=electrochemistry&option=203" rel="nofollow">electrochemistry;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=electrogravimetry&option=203" rel="nofollow">electrogravimetry;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=ion transport&option=203" rel="nofollow">ion transport;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=vapor coatings&option=203" rel="nofollow">vapor coatings;</a> </p> <div class="translation"> 机译：导电聚合物;电化学;电解中;离子运输;蒸气涂料; 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tuijian_authcolor">,熊华玉</a> <span> <a href="/journal-cn-4612/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 湖北大学学报（自然科学版） </a> </span> <span> . 2016</span><span>,第006期</span> </span> </div> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-conference-cn_meeting-39312_thesis/020222422597.html">自制电化学氧化中和装置用于离子色谱法测定紫菜中的碘</a> <b>[C]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=董瑞&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 董瑞</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=祝建华&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,祝建华</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=刘艳明&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,刘艳明</a> <span> <a href="/conference-cn-39312/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 第四届环渤海色谱质谱学术报告会 </a> <span> <span> . 2016</span> </span> </div> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/020315274272.html">基于铅离子依赖性DNA酶构建磁控诱导电化学适体传感器及血清凝血酶的检测</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=朱春红&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 朱春红</a> <span> . 2019</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/06120100949641.html">一种银纳米颗粒掺杂的高性能光致聚合物薄膜材料及制备和应用</a> <b>[P]</b> . <span> 中国专利： CN110045577A </span> <span> . 2019-07-23</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/06120901849.html">使用阴离子交换树脂和pH依赖性表面活性剂从含氟聚合物分散体中移除氟化乳化剂的方法和含有pH依赖性表面活性剂的含氟聚合物分散体</a> <b>[P]</b> . <span> 中国专利： CN101668783B </span> <span> . 2012.03.28</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130403340856.html">Halogen doping source for doping oxide thin film with halogen using atomic layer deposition method for manufacturing the halogen doping source method for doping oxide thin film with halogen using atomic layer deposition and oxide thin film doped with halogen manufactured by using the method for doping oxide thin film with halogen</a> <b>[P]</b> . <span> 外国专利：  KR101933727B1 </span> <span> . 2018-12-31</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：用于通过使用原子层沉积方法向氧化物薄膜掺杂卤素的卤素掺杂源，用于制造卤素用于通过使用原子层沉积来对氧化物薄膜进行卤素掺杂的卤素掺杂源的方法，以及通过使用用于掺杂氧化物薄膜的方法制造的掺杂卤素的氧化物薄膜。含卤素 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130411514570.html">HALOGEN DOPING SOURCE FOR DOPING PART OF OXIDE THIN FILM WITH HALOGEN ELEMENT USING ATOMIC LAYER DEPOSITION, METHOD FOR MANUFACTURING HALOGEN DOPING SOURCE, METHOD FOR DOPING PART OF OXIDE THIN FILM WITH HALOGEN ELEMENT SOURCE USING ATOMIC LAYER DEPOSITION, AND OXIDE THIN FILM DOPED WITH HALOGEN MANUFACTURED BY USING METHOD FOR DOPING OXIDE THIN FILM WITH HALOGEN</a> <b>[P]</b> . <span> 外国专利：  KR20160042405A </span> <span> . 2016-04-19</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：用于原子层沉积的带有氧化物元素的氧化物薄膜部分的卤化物掺杂源，用于制造卤素掺杂源的方法，具有用于沉积的氧化物层的原子层材料的氧化物与薄膜的掺杂的方法用卤代氧掺杂氧化薄膜的方法 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130413108573.html">Halogen doping source that a part of the oxide film may be doped with a halogen in atomic layer deposition, an oxide thin film by the halogen method of manufacturing a doping source, and by utilizing the halogen source atomic layer deposition halogen-doped oxide films part has been formed using the method and process doped with halogen</a> <b>[P]</b> . <span> 外国专利：  JP5965441B2 </span> <span> . 2016-08-03</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：卤素掺杂源，其在原子层沉积中可以用卤素掺杂氧化物膜的一部分，通过制造掺杂源的卤素方法，并通过利用卤素源原子层沉积卤素掺杂的氧化物膜部分，氧化物薄膜用掺杂卤素的方法和工艺形成 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 class="all_title" id="enpatent55">相关主题</h3> <ul id="subject"> </ul> </div> </div> </div> </div> <div class="right rightcon"> <div class="details_img cardcommon clearfix" style="margin-bottom: 10px;display:none;" > </div> </div> </div> <div id="thesis_get_original1" class="downloadBth" style="bottom: 19px;z-index: 999;" onclick="ywcd('0704022435905','4',7,2,1,'',this,24)" class="delivery" prompt="010401" title="通过人工服务将文献原文发送至邮箱" >获取原文</div> <div class="journalsub-pop-up" style="display: none"> <div class="journal-sub"> <h2>期刊订阅</h2> <img src="https://cdn.zhangqiaokeyan.com/img/loginclose.png" alt="关闭" 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