Direct In Situ Observation of the Early‐Stage Disorder–Order Evolution of Perpendicular Lamellae in Thermally Annealed High‐χ Block Copolymer Thin Films

Chandra Alvin; Nakatani Ryuichi; Uchiyama Takumi; Seino Yuriko; Sato Hironobu; Kasahara Yusuke; Azuma Tsukasa; Hayakawa Teruaki

摘要

Abstract > The evolution of well‐ordered, sub‐10 nm, perpendicular lamellae from a disordered state is documented directly using in situ atomic force microscopy, cross‐sectional scanning electron microscopy, and grazing‐incidence small angle X‐ray scattering. Since block copolymer (BCP) self‐assembly occurs on extremely fast time scales, directly imaging the growth of perpendicular lamellae remains challenging. The lack of understanding behind early‐stage self‐assembly and how metastable defects can affect the kinetic behavior near thermodynamic equilibrium prevents the realization of defect‐free thin films. By characterizing the evolution of nanostructures using a high‐χ, perpendicular lamella‐forming BCP, poly(polyhedral oligomeric silsesquioxane)‐ block ‐poly(2,2,2‐trifluoroethyl methacrylate), over a wide temperature range, three stages in the evolution of perpendicular lamellae, characterized mainly by the root‐mean‐squared (rms) roughness, is observed. At temperatures lower than the glass transition temperatures ( T <sub>g</sub> ), the film retains a smooth, disordered surface (rms roughness = 0.352 ± 0.006 nm), characteristic of spin‐coated films. Near the T <sub>g</sub> , spinodal decomposition and the appearance of lamellae are detected as the rms roughness increases at 70 °C, before peaking at 82 °C at 0.83 nm, and decaying rapidly with increasing temperatures. Above the T <sub>g</sub> , the rms roughness returns to 0.35 ± 0.03 nm, as defects are observed to annihilate sequentially. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> > 从紊乱的状态下垂直于10nm，垂直薄片的垂直薄片的演变直接使用原位原子力显微镜，横截面扫描电子显微镜和放牧发生小角度X射线散射进行记录。由于嵌段共聚物（BCP）自组装发生在极快的时间尺度上，因此直接成像垂直薄片的生长仍然挑战。早期自我组装背后的理解缺乏理解以及常规缺陷如何影响热力学平衡附近的动力学行为可防止无缺陷薄膜的实现。通过使用高χ，垂直薄片形成BCP，聚（多面体低聚硅氧烷）来表征纳米结构的演化 - 块</ i> - 聚（2,2,2-三氟甲基丙烯酸甲酯），在宽温度范围内，观察到垂直薄片的进化中的三个阶段，其特征主要是由根平均平方（RMS）粗糙度的粗糙度。在低于玻璃化转变温度的温度下（ t </ i> <sub> g </ sub> ），薄膜保留光滑，无序的表面（RMS粗糙度= 0.352±0.006nm），旋涂膜的特性。靠近 t </ i> <sub> g </ sub> 当RMS粗糙度在70℃下增加时，检测旋光板分解和薄片的外观，在82℃下在0.83nm处达到峰值，并随着温度的增加速度衰减。以上 t </ i> <sub> g </ sub> ，RMS粗糙度返回0.35±0.03nm，因为观察到依次湮灭缺陷。 </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-18063/'>《Advanced materials interfaces》</a> <b style="margin: 0 2px;">|</b><span>2019年第11期</span><b style="margin: 0 2px;">|</b><span>共7页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Chandra Alvin&option=202" target="_blank" rel="nofollow">Chandra Alvin;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Nakatani Ryuichi&option=202" target="_blank" rel="nofollow">Nakatani Ryuichi;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Uchiyama Takumi&option=202" target="_blank" rel="nofollow">Uchiyama Takumi;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Seino Yuriko&option=202" target="_blank" rel="nofollow">Seino Yuriko;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Sato Hironobu&option=202" target="_blank" rel="nofollow">Sato Hironobu;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Kasahara Yusuke&option=202" target="_blank" rel="nofollow">Kasahara Yusuke;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Azuma Tsukasa&option=202" target="_blank" rel="nofollow">Azuma Tsukasa;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Hayakawa Teruaki&option=202" target="_blank" rel="nofollow">Hayakawa Teruaki;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Department of Materials Science and EngineeringTokyo Institute of Technology2‐12‐1‐S8‐36 Ookayama Meguro‐ku Tokyo 152–8552 Japan;</p> <p>Department of Materials Science and EngineeringTokyo Institute of Technology2‐12‐1‐S8‐36 Ookayama Meguro‐ku Tokyo 152–8552 Japan;</p> <p>Department of Materials Science and EngineeringTokyo Institute of Technology2‐12‐1‐S8‐36 Ookayama Meguro‐ku Tokyo 152–8552 Japan;</p> <p>Evolving Nano‐process Infrastructure Development Center16‐1 Onogawa Tsukuba‐shi Ibaraki 305‐8569 Japan;</p> <p>Evolving Nano‐process Infrastructure Development Center16‐1 Onogawa Tsukuba‐shi Ibaraki 305‐8569 Japan;</p> <p>Evolving Nano‐process Infrastructure Development Center16‐1 Onogawa Tsukuba‐shi Ibaraki 305‐8569 Japan;</p> <p>Evolving Nano‐process Infrastructure Development Center16‐1 Onogawa Tsukuba‐shi Ibaraki 305‐8569 Japan;</p> <p>Department of Materials Science and EngineeringTokyo Institute of Technology2‐12‐1‐S8‐36 Ookayama Meguro‐ku Tokyo 152–8552 Japan;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/6960.html" title="特种结构材料">特种结构材料;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=block copolymers&option=203" rel="nofollow">block copolymers;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=in situ atomic force microscopy (AFM)&option=203" rel="nofollow">in situ atomic force microscopy (AFM);</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=perpendicular lamellae&option=203" rel="nofollow">perpendicular lamellae;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=self‐assembly&option=203" rel="nofollow">self‐assembly;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=spinodal decomposition&option=203" rel="nofollow">spinodal decomposition;</a> </p> <div class="translation"> 机译：嵌段共聚物;原位原子力显微镜（AFM）;垂直薄片;自组装;旋转晶片分解; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704022434538.html">Direct In Situ Observation of the Early‐Stage Disorder–Order Evolution of Perpendicular Lamellae in Thermally Annealed High‐χ Block Copolymer Thin Films</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Chandra Alvin&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Chandra Alvin,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Nakatani Ryuichi&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Nakatani Ryuichi,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Uchiyama Takumi&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Uchiyama Takumi,</a> <a href="/journal-foreign-18063/" target="_blank" rel="nofollow" class="tuijian_authcolor">Advanced materials interfaces .</a> <span>2019</span><span>,第11期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：直接原位观察垂直薄片在热退火高嵌段共聚物薄膜中垂直薄膜的早期紊乱顺序演化</span> </p> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704018556236.html">Lamellar Diblock Copolymer Thin Films during Solvent Vapor Annealing Studied by GISAXS: Different Behavior of Parallel and Perpendicular Lamellae</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Jianqi Zhang&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Jianqi Zhang,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Dorthe Posselt&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Dorthe Posselt,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Detlef-M. Smilgies&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Detlef-M. Smilgies,</a> <a href="/journal-foreign-24255/" target="_blank" rel="nofollow" class="tuijian_authcolor">Macromolecules .</a> <span>2014</span><span>,第16期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：GISAXS研究的溶剂蒸气退火过程中的层状二嵌段共聚物薄膜：平行和垂直薄片的不同行为</span> </p> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/070406252969.html">Structural evolution of perpendicular lamellae in diblock copolymer thin films during solvent vapor treatment investigated by grazing-incidence small-angle X-ray scattering</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zhang J.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Zhang J.,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Posselt D.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Posselt D.,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Sepe A.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Sepe A.,</a> <a href="/journal-foreign-24279/" target="_blank" rel="nofollow" class="tuijian_authcolor">Macromolecular rapid communications: Publishing the newsletters of the European Polymer Federation .</a> <span>2013</span><span>,第16期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：掠入射小角X射线散射研究二嵌段共聚物薄膜在溶剂蒸汽处理过程中垂直片层的结构演变</span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/academic-conference-foreign_international-symposium-polymer-physics-pp2002_thesis/020511204760.html">AFM ex-situ observation of thermally induced morphology evolution in a triblock copolymer thin film</a> <b>[C]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> </a> <a href="/conference-foreign-16944/" target="_blank" rel="nofollow" class="tuijian_authcolor">International symposium on polymer physics(PP'2002) .</a> <span>2002</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：三嵌段共聚物薄膜中热诱导形态演变的AFM异位观察</span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/academic-degree-foreign_mphd_thesis/02061221946.html">Manipulating block copolymer self-assemblies in bulk and thin films by thermal and solvent annealing.</a> <b>[D] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Gu, Weiyin.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Gu, Weiyin. </a> <span>2013</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：通过热退火和溶剂退火处理嵌段共聚物在块状和薄膜中的自组装。</span> </p> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-journal-foreign-pmc_acs-authorchoice_thesis/040004895768.html">Lamellar Diblock Copolymer Thin Films during SolventVapor Annealing Studied by GISAXS: Different Behavior of Paralleland Perpendicular Lamellae</a> <b>[O] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Jianqi Zhang&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Jianqi Zhang,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=*&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">*,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Dorthe Posselt&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Dorthe Posselt,</a> <span>-1</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：溶剂中的层状二嵌段共聚物薄膜GISAXS研究的蒸汽退火：并联的不同行为和垂直薄片</span> </p> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/open-access_resources_thesis/01000128632769.html">Self-Assembly: Direct In Situ Observation of the Early-Stage Disorder-Order Evolution of Perpendicular Lamellae in Thermally Annealed High-χ Block Copolymer Thin Films (Adv. Mater. Interfaces 11/2019)</a> <b>[O] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Alvin Chandra&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Alvin Chandra,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ryuichi Nakatani&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Ryuichi Nakatani,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Takumi Uchiyama&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Takumi Uchiyama,</a> <span>2019</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：自组装：直接出于原位观察热退火高嵌段共聚物垂直薄膜垂直薄膜的早期紊乱顺序演化（ADV。母体。界面11/2019）</span> </p> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/academic-journal-cn_journal-dalian-polytechnic-university_thesis/020128874452.html">嵌段共聚物薄膜中大长径比柱状相的垂直取向</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=何迎新&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 何迎新</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=李轶文&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,李轶文</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=赵娜&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,赵娜</a> <span> <a href="/journal-cn-7502/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 大连工业大学学报 </a> </span> <span> . 2014</span><span>,第005期</span> </span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/academic-journal-cn_applied-chemical-industry_thesis/0201248380017.html">嵌段共聚物薄膜自组装热退火技术进展</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=刘冬梅&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 刘冬梅</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=李海英&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,李海英</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=雷良才&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,雷良才</a> <span> <a href="/journal-cn-9217/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 应用化工 </a> </span> <span> . 2016</span><span>,第004期</span> </span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/academic-journal-cn_detail_thesis/0201296008382.html">聚苯乙烯-聚甲基丙烯酸甲酯两嵌段共聚物薄膜在超临界二氧化碳和丙酮溶剂耦合作用下的形貌演化</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=李亚南&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 李亚南</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=李妍凝&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,李妍凝</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=诸婷婷&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,诸婷婷</a> <span> <a href="/journal-cn-56862/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 高分子材料科学与工程 </a> </span> <span> . 2017</span><span>,第2期</span> </span> </div> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/academic-journal-cn_chemical-research_thesis/0201290385951.html">嵌段共聚物自组装薄膜中纳米结构的形成及应用</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=刘雨微&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 刘雨微</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=崔晓娜&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,崔晓娜</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=韩铭&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,韩铭</a> <span> <a href="/journal-cn-12031/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 化学研究 </a> </span> <span> . 2021</span><span>,第003期</span> </span> </div> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/academic-journal-cn_journal-semiconductors_thesis/0201297005675.html">热退火对分子束外延生长的高纯GaAs薄膜中深能级的影响</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=徐鸿达&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 徐鸿达</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=T.G.Andersson&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,T.G.Andersson</a> <span> <a href="/journal-cn-50336/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 半导体学报：英文版 </a> </span> <span> . 1989</span><span>,第12期</span> </span> </div> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-conference-cn_meeting-26770_thesis/020221701506.html">在嵌段共聚物本体与薄膜中结晶形貌的研究</a> <b>[C]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=陈冬菊&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 陈冬菊</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=张发军&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,张发军</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=宫玉梅&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,宫玉梅</a> <span> <a href="/conference-cn-26770/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 2005年全国高分子学术论文报告会 </a> <span> <span> . 2005</span> </span> </div> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/020315669563.html">超薄膜中嵌段共聚物自组装取向图案构筑及结晶熔融行为研究</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=张恒&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 张恒</a> <span> . 2020</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/06120107963392.html">使用其单体至少部分地不同于嵌段共聚物的各嵌段中存在的单体的统计或梯度共聚物将嵌段共聚物的纳米畴垂直取向的方法</a> <b>[P]</b> . <span> 中国专利： CN105492971A </span> <span> . 2016-04-13</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/061202516666.html">一种垂直取向自组装的嵌段共聚物薄膜的制备方法及其制品和用途</a> <b>[P]</b> . <span> 中国专利： CN104829854B </span> <span> . 2017.07.21</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130500625958.html">INSTALLATION FOR HIGH-TEMPERATURE VACUUM ANNEALING OF THIN FILMS WITH POSSIBILITY OF IN SITU OPTICAL OBSERVATION WITH HIGH RESOLUTION</a> <b>[P]</b> . <span> 外国专利：  RU2755405C1 </span> <span> . 2021-09-15</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：具有高分辨率原位光学观察的薄膜高温真空退火的安装 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130412546436.html">Thermal anneal of block copolymer films with top interface constrained to wet both blocks with equal preference</a> <b>[P]</b> . <span> 外国专利：  US9315609B2 </span> <span> . 2016-04-19</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：具有顶部界面的嵌段共聚物薄膜的热退火被约束为以相同的优先权润湿两个嵌段 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130414712425.html">THERMAL ANNEAL OF A BLOCK COPOLYMER FILMS WITH TOP INTERFACE CONSTRAINED TO WET BOTH BLOCKS WITH EQUAL PREFERENCE</a> <b>[P]</b> . <span> 外国专利：  EP2281299B1 </span> <span> . 2014-12-10</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：顶部界面受湿性均等的两个嵌段的嵌段共聚物膜的热退火 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 class="all_title" id="enpatent55">相关主题</h3> <ul id="subject"> </ul> </div> </div> </div> </div> <div class="right rightcon"> <div class="details_img cardcommon clearfix" style="margin-bottom: 10px;display:none;" > </div> </div> </div> <div id="thesis_get_original1" class="downloadBth" style="bottom: 19px;z-index: 999;" onclick="ywcd('0704022434538','4',7,2,1,'',this,24)" class="delivery" prompt="010401" title="通过人工服务将文献原文发送至邮箱" >获取原文</div> <div class="journalsub-pop-up" style="display: none"> <div class="journal-sub"> <h2>期刊订阅</h2> <img src="https://cdn.zhangqiaokeyan.com/img/loginclose.png" alt="关闭" onclick="$('.journalsub-pop-up').hide()"> <p class="pardon">抱歉，该期刊暂不可订阅，敬请期待！</p> <p class="current">目前支持订阅全部北京大学中文核心（2020）期刊目录。</p> <div style="display: flex;margin-top: 69px;justify-content: space-between;"> <div class="no-sub" onclick="$('.journalsub-pop-up').hide()">暂不订阅</div> <div class="other-sub" onclick="continueSub('from=pc-detail')">继续订阅其他期刊</div> </div> </div> </div> <div class="right_btn"> <ul> <li class="gouwuche">  </li> <li class="yijian"> <a href="javascript:void(0);" onclick="link_analysis('/mycenter/auth/complaint.html',this)" title="意见反馈">意见反馈</a> </li> <li class="top"> <a href="javascript:scrollTo(0,0);" title="回到顶部">回到顶部</a> </li> <li class="shouye"> <a href="/" title="首页">回到首页</a> </li> </ul> </div> <div class="xllindexfooter"> <div class="xllindexfootercenter"> <div class="xllindexfooterleft left" > <div class="xllindexfooterleftli"> <ul> <li><a href="/about.html" title="关于掌桥">关于掌桥</a></li> <li><a href="/help/helpmap.html" title="资源导航">资源导航</a></li> <li><a href="/help/helpguide.html" title="新手指南">新手指南</a></li> <li><a href="/help/helpcenter.html" title="常见问题">常见问题</a></li> <li><a href="/sitemap.html" title="网站地图">网站地图</a></li> <li><a href="/help/helpcenter.html?type=9" title="版权声明">版权声明</a></li> </ul> </div> <div class="xllindexfooterleft"> <p class="xllindexfooterlefteamil">客服邮箱：kefu@zhangqiaokeyan.com</p> <div class="xllindexfooterlefttcp"> <div class="xllindexfooterpoliceiimg"></div> <div class="xllindexfooterpoliceispan"> <span>京公网安备：11010802029741号 </span> <span>ICP备案号：<a href="https://beian.miit.gov.cn" rel="nofollow" target="_blank" title="ICP备案号">京ICP备15016152号-6</a></span> <span>六维联合信息科技 (北京) 有限公司©版权所有</span> </div> </div> </div> </div> <div class="xllindexfooterright left"> <ul> <li> <p style="font-weight: bold;">客服微信</p> <div></div> </li> <li> <p style="font-weight: bold;">服务号</p> <div></div> </li> </ul> </div> </div> </div> <span id="0704022434538down" data-source="7," data-out-id="2faZZCJMGSSFprzPCCledzG61kneyKmhq0lBQhXCljsJivbHeFqTlFgkbMyQPVz2," data-f-source-id="7" data-title="Direct In Situ Observation of the Early‐Stage Disorder–Order Evolution of Perpendicular Lamellae in Thermally Annealed High‐χ Block Copolymer Thin Films" data-price="20" data-site-name="" data-transnum="24" style="display:none;"></span> <input type="hidden" value="4" id="sourcetype"> <input type="hidden" value="18063" id="journalid"> <input type="hidden" value="1" id="inyn_provide_service_level"> <input type="hidden" value="https://cdn.zhangqiaokeyan.com" id="imgcdn"> <input type="hidden" value="1" id="isdeatail"> <input type="hidden" value="" id="syyn_indexed_database"> <input type="hidden" value="" id="servicetype"> <input type="hidden" id="pagename" value="Direct In Situ Observation of the Early‐Stage Disorder–Order Evolution of Perpendicular Lamellae in Thermally Annealed High‐χ Block Copolymer Thin Films"/> <input type="hidden" value="thesis_get_original" id="pageIdentification"> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/jquery-1.12.4.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/lwlh_ajax.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/zq.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/common.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/jquery.cookie.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/top.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/tip.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/login.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/down.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/search.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/newmail.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/searchtype.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/user/regist.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/zxs_solor/detail.js?v=5.7.8"></script> <script type="text/javascript" src="https://www.zhangqiaokeyan.com/statistics/static/pagecollection.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/tj.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/sse.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/pushbaidu.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/history.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/util/cookie.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/weipu/weipu.js?v=5.7.8"></script> </body> <script> function kefu(customization) { var from = GetQueryString("from"); if (from == null || from == "") { from = "other"; } var url = getWxWorkQrCode(55, from, customization); if (url == "" || typeof url == 'undefined') { url = "https://wework.qpic.cn/wwpic/994838_0LUTS-VqR0quT1N_1675665967/0"; } tipDocGuidance(url, '人工辅助获取外文期刊材料'); } $(function(){ var weiPuStatus = getCookie('WeiPuStatus'); if(weiPuStatus){ tipWeiPuStatus(weiPuStatus); delCookie('WeiPuStatus'); } getFacetKeywordVoInId(); var sourcetype = $("#sourcetype").val(); var inyn_provide_service_level = $("#inyn_provide_service_level").val(); if((sourcetype ==1||sourcetype==4)&&inyn_provide_service_level!=4){ getJournal(); } }) </script> </html>