Block Copolymer‐Templated Approach to Nanopatterned Metal–Organic Framework Films

Zhou Meimei; Wu Yi‐nan; Wu Baozhen; Yin Xianpeng; Gao Ning; Li Fengting; Li Guangtao

摘要

Abstract > The fabrication of patterned metal–organic framework (MOF) films with precisely controlled nanoscale resolution has been a fundamental challenge in nanoscience and nanotechnology. In this study, nanopatterned MOF films were fabricated using a layer‐by‐layer (LBL) growth method on functional templates (such as a bicontinuous nanoporous membrane or a structure with highly long‐range‐ordered nanoscopic channels parallel to the underlying substrate) generated by the microphase separation of polystyrene‐ b ‐poly(2‐vinylpyridine) (PS‐ b ‐P2VP) block copolymers. HKUST‐1 can be directly deposited on the templates without any chemical modification because the pyridine groups in P2VP interact with metal ions via metal‐BCP complexes. As a result, nanopatterned HKUST‐1 films with feature sizes below 50?nm and controllable thicknesses can be fabricated by controlling the number of LBL growth cycles. The proposed fabrication method further extends the applications of MOFs in various fields. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract XMLNS =“http://www.wiley.com/namespaces/wiley”type =“main”xml：lang =“en”> <标题类型=“main”>抽象</ title> > 具有精确控制的纳米级分辨率的图案化金属 - 有机框架（MOF）膜的制造是纳米科学和纳米技术的基本挑战。在该研究中，使用逐层（LBL）生长方法在功能模板（例如具有与底层基底平行的高度长的纳米镜通道的结构）上制造纳米透明理由的MOF膜通过聚苯乙烯的微相分离 - b </ i> - 聚（2-乙烯基吡啶）（ps- b </ i> -P2VP）嵌段共聚物。由于P2VP中的吡啶基团通过金属-BCP络合物，可以直接沉积在模板上而没有任何化学改性。结果，通过控制LBL生长循环的数量，可以制造具有低于50Ω·NM和可控厚度的特征尺寸的纳米透明型HKUST-1膜。所提出的制造方法进一步延伸了MOF在各种领域的应用。 </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-16161/'>《Chemistry, an Asian journal》</a> <b style="margin: 0 2px;">|</b><span>2017年第16期</span><b style="margin: 0 2px;">|</b><span>共4页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zhou Meimei&option=202" target="_blank" rel="nofollow">Zhou Meimei;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Wu Yi‐nan&option=202" target="_blank" rel="nofollow">Wu Yi‐nan;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Wu Baozhen&option=202" target="_blank" rel="nofollow">Wu Baozhen;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Yin Xianpeng&option=202" target="_blank" rel="nofollow">Yin Xianpeng;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Gao Ning&option=202" target="_blank" rel="nofollow">Gao Ning;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Li Fengting&option=202" target="_blank" rel="nofollow">Li Fengting;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Li Guangtao&option=202" target="_blank" rel="nofollow">Li Guangtao;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>College of Environmental Science &</p> <p>EngineeringTongji University1239 Siping Road Shanghai 200092 China) Fax: (+86)?21-659-850-59;</p> <p>College of Environmental Science &</p> <p>EngineeringTongji University1239 Siping Road Shanghai 200092 China) Fax: (+86)?21-659-850-59;</p> <p>College of Environmental Science &</p> <p>EngineeringTongji University1239 Siping Road Shanghai 200092 China) Fax: (+86)?21-659-850-59;</p> <p>Department of ChemistryTsinghua UniversityBeijing 100084 China) Fax: (+86)?10-627-929-05;</p> <p>Department of ChemistryTsinghua UniversityBeijing 100084 China) Fax: (+86)?10-627-929-05;</p> <p>College of Environmental Science &</p> <p>EngineeringTongji University1239 Siping Road Shanghai 200092 China) Fax: (+86)?21-659-850-59;</p> <p>Department of ChemistryTsinghua UniversityBeijing 100084 China) Fax: (+86)?10-627-929-05;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/159.html" title="化学">化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=block copolymers&option=203" rel="nofollow">block copolymers;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=layer-by-layer&option=203" rel="nofollow">layer-by-layer;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=metal-organic frameworks&option=203" rel="nofollow">metal-organic frameworks;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=nanopatterns&option=203" rel="nofollow">nanopatterns;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=self-assembly&option=203" rel="nofollow">self-assembly;</a> </p> <div class="translation"> 机译：嵌段共聚物;逐层;金属 - 有机框架;纳米模式;自我组装; 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