Copper-Catalyzed Coupling of Acyl Chlorides with gem-Difluorinated Organozinc Reagents via Acyl Dithiocarbamates

Salavat S. Ashirbaev; Vitalij V. Levin; Marina I. Struchkova; Alexander D. Dilman

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Copper-Catalyzed Coupling of Acyl Chlorides with gem-Difluorinated Organozinc Reagents via Acyl Dithiocarbamates

机译：通过酰基二硫代氨基甲酸烷基酯与酰氯酰氯铜氯化物与氟化有机锌试剂的铜催化偶联

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A cross-coupling of acyl chlorides with gem -difluorinated organozinc reagents affording difluorinated ketones is described. In the reaction, acyl chlorides are first treated with potassium dithiocarbamate to generate S-acyl dithiocarbamates, which couple with organozincs in the presence of a copper(I) catalyst.

机译：描述了酰胺与珠宝酰氯的交联酰氯，其与二氟化酮提供过二氟化酮的有机锌试剂。在反应中，首先用二硫代氨酸钾处理酰氯以产生S-酰基二硫代氨酸酯，在铜（I）催化剂存在下加上有机锆。

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《The Journal of Organic Chemistry》 |2018年第1期|共6页
作者
Salavat S. Ashirbaev; Vitalij V. Levin; Marina I. Struchkova; Alexander D. Dilman;
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作者单位

N. D. Zelinsky Institute of Organic Chemistry 119991 Moscow Leninsky prosp. 47 Russian Federation;

N. D. Zelinsky Institute of Organic Chemistry 119991 Moscow Leninsky prosp. 47 Russian Federation;

N. D. Zelinsky Institute of Organic Chemistry 119991 Moscow Leninsky prosp. 47 Russian Federation;

N. D. Zelinsky Institute of Organic Chemistry 119991 Moscow Leninsky prosp. 47 Russian Federation;

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中图分类有机化学;
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1. Copper-Catalyzed Coupling of Acyl Chlorides with gem-Difluorinated Organozinc Reagents via Acyl Dithiocarbamates [J] . Salavat S. Ashirbaev, Vitalij V. Levin, Marina I. Struchkova, The Journal of Organic Chemistry . 2018,第1期

机译：通过酰基二硫代氨基甲酸烷基酯与酰氯酰氯铜氯化物与氟化有机锌试剂的铜催化偶联
2. Pd(0)/C-catalyzed cross-couplings of acyl chlorides with triarylbismuths as atom-efficient sub-stoichiometric multi-coupling reagents [J] . Maddali L N. Rao, Deepak N. Jadhav, Varadhachari Venkatesh Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2009,第29期

机译：Pd（0）/ C催化的酰氯与三芳基铋的交叉偶联作为原子有效的亚化学计量多重偶联试剂
3. Copper-catalyzed three-component reactions of phenols, acyl chlorides and Wittig reagents for the synthesis of beta-aryloxyl acrylates [J] . Zhang Yi, Liu Yunyun, Wan Jie-Ping New Journal of Chemistry . 2015,第3期

机译：铜催化的酚，酰氯和Wittig试剂的三组分反应，用于合成β-芳氧基丙烯酸酯
4. Aminohydroxyphosphine Ligand for Copper-Catalyzed Enantioselective Conjugate Addition of Organozinc Reagents [C] . Naohiko Yoshikai, Alakananda Hajra, Eiichi Nakamura Symposium on Organometallic Chemistry . 2006

机译：用于铜催化的致剂偶联缀合物的氨基羟基膦配体加入有机夹试剂
5. Part I. Acyl cyanide coupling reactions and the synthesis of β-tricarbonyl natural products. Part II. Oxidation of heteroatom-containing substrates with hypervalent iodine(V) reagents [D] . Mathison, Casey Jacob Nelson 2007

机译：第一部分：酰基氰偶联反应和β-三羰基天然产物的合成。第二部分用高价碘（V）试剂氧化含杂原子的底物
6. A practical route to tertiary diarylmethylamides or -carbamates from imines organozinc reagents and acyl chlorides or chloroformates [O] . Erwan Le Gall, Antoine Pignon, Thierry Martens 2011

机译：从亚胺有机锌试剂和酰氯或氯甲酸酯到叔二芳基甲基酰胺或氨基甲酸酯的实用方法
7. A practical route to tertiary diarylmethylamides or -carbamates from imines, organozinc reagents and acyl chlorides or chloroformates [O] . Erwan Le Gall, Antoine Pignon, Thierry Martens 2011

机译：从亚胺，有机锌试剂和酰氯或氯甲酸酯制备叔二芳基甲基酰胺或氨基甲酸酯的实用方法

Copper-Catalyzed Coupling of Acyl Chlorides with gem-Difluorinated Organozinc Reagents via Acyl Dithiocarbamates

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