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Research and application of a high-performance fluorocarbon plate preparedviamodified a high temperature mould pressing method

机译:高性能氟碳板的研究与应用制备了viamodized高温模压法

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摘要

As an indispensable part of the production of electrolytic fluorine, the quality of the carbon plate determines the running conditions and technical and economic indexes of electrolytic cells. Therefore, improving the service life of carbon plates has become an urgent challenge. Herein, special fluorocarbon plates were successfully preparedviadirect heating and asphalt impregnation based on the resistance of the carbon plates, which not only improved their performance index, but also greatly reduced the cost of their production. According to electron microscopy (SEM) observation, the carbon plate prepared by the hot pressing method possessed a more compact internal structure and dislocation phenomenon, which reduced the contact pores between particles, increased the density and reduced the resistivity. The prepared carbon plate exhibited a density of 1.81 g cm(-3), resistivity of 25.8 mu omega m, and service life of 151 days. These results are superior to that of industrial carbon plates with a density of 1.74 g m(-3), resistivity of 36.7 mu omega m, and run time of 90 days, where our fabricated carbon plate exhibited an improvement of 4.5%, 29.7%, and 67.7%, respectively.
机译:作为电解氟生产的不可或缺的一部分,碳板的质量决定了电解细胞的运行条件和技术和经济指标。因此,提高碳板的使用寿命已成为一种紧迫的挑战。在此,基于碳板的电阻成功制备了特殊的碳氟化碳板,其基于碳板的电阻,这不仅改善了它们的性能指标,而且大大降低了生产成本。根据电子显微镜(SEM)观察,通过热压方法制备的碳板具有更紧凑的内部结构和位错现象,其减少了颗粒之间的接触孔,增加了密度并降低了电阻率。制备的碳板具有1.81g cm(-3)的密度,电阻率为25.8μmomegam,使用寿命为151天。这些结果优于一个密度为1.74克(-3)的工业碳板,36.7μmomegam的电阻率,并运行时间为90天,其中我们的制造碳板显示出4.5%,29.7%,分别为67.7%。

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  • 来源
    《RSC Advances》 |2020年第53期|共11页
  • 作者单位

    Sichuan Univ Chem Sci &

    Engn Coll Chengdu 610065 Peoples R China;

    Sichuan Univ Chem Sci &

    Engn Coll Chengdu 610065 Peoples R China;

    Sichuan Univ Chem Sci &

    Engn Coll Chengdu 610065 Peoples R China;

    Sichuan Univ Chem Sci &

    Engn Coll Chengdu 610065 Peoples R China;

    Sichuan Univ Chem Sci &

    Engn Coll Chengdu 610065 Peoples R China;

    Sichuan Univ Chem Sci &

    Engn Coll Chengdu 610065 Peoples R China;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 化学;
  • 关键词

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