<![CDATA[Magnetic properties of the anion-radical salts [M(bipy) <ce:inf loc='post'>3</ce:inf>](TCNQ) <ce:inf loc='post'>4</ce:inf>·X, where M?=?Co, Ni, Zn and X?=?H <ce:inf loc='post'>2</ce:inf>O or (CH <ce:inf loc='post'>3</ce:inf>) <ce:inf loc='post'>2</ce:inf>CO]]>

D. ?oltésová; G. Vasylets; E. ?i?már; A.V. Fedorchenko; V. Starodub; V. Medviediev; O. Shishkin; O. Bukrynov; A. Feher

首页> 外文期刊>Inorganica Chimica Acta >3](TCNQ) 4·X, where M?=?Co, Ni, Zn and X?=?H 2O or (CH 3) 2CO]]>

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3](TCNQ) 4·X, where M?=?Co, Ni, Zn and X?=?H 2O or (CH 3) 2CO]]>

机译：<！[cdata [阴离子 - 自由基盐的磁性[m（bipy） 3 ]（tcnq） 4 x，其中m？=？co，ni，zn和x？place =“post”> 3 ） 2 CO]]>

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Graphical abstract

Stacking of TCNQ molecules in anion-radical salt [Co(bipy)3](TCNQ)4·H2O.

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?Novel anion-radical salt [Co(bipy)3](TCNQ)4·H2O has been synthesized and the crystal structure was solved.

?Co2+ions have been observed in spin-admixed state.

?EPR spectra of investigated compounds exhibit thermally activated transitions originating from dimerized states of TCNQ.

Abstract

An anion-radical salt (ARS) [Co(bipy)3

机译：<！[CDATA [ 图形抽象 TCNQ分子的堆叠中阴离子基团的盐[CO（联吡啶） 3 ]（TCNQ） 4 ·H 2 0 显示中省略亮点新型阴离子自由基盐[CO（BIP Y） 3 ]（TCNQ） 4 ·H 2 0已经合成和晶体结构来解决钴 2 + 离子已经在旋混合观察。状态 <？CE：对ID = “P0015” 视图= “所有”> EPR研究化合物的光谱从TCNQ的二聚态表现出热活化过渡始发 < / CE：抽象秒> 抽象一种阴离子基团的盐（ARS）[CO（联吡啶） 3

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来源
《Inorganica Chimica Acta 》 |2018年第2018期| 共8页
作者
D. ?oltésová; G. Vasylets; E. ?i?már; A.V. Fedorchenko; V. Starodub; V. Medviediev; O. Shishkin; O. Bukrynov; A. Feher;
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作者单位

Institute of Physics Faculty of Science P. J. ?afárik University;

Applied Chemistry Department V. N. Karazin Kharkiv National University;

Institute of Physics Faculty of Science P. J. ?afárik University;

Institute of Physics Faculty of Science P. J. ?afárik University;

Institute of Chemistry Jan Kochanowski University;

Institute of Low Temperature and Structure Research Polish Academy of Sciences;

SSI “Institute for Single Crystals” National Academy of Science of Ukraine;

Applied Chemistry Department V. N. Karazin Kharkiv National University;

Institute of Physics Faculty of Science P. J. ?afárik University;

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原文格式 PDF
正文语种 eng
中图分类无机化学 ;
关键词
Anion-radical salt; Magneto-structural correlations; Metal–radical interaction;

机译：阴离子 - 自由基盐;磁结构相关;金属 - 自由基相互作用;

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3](TCNQ) 4·X, where M?=?Co, Ni, Zn and X?=?H 2O or (CH 3) 2CO]]>

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