Synthesis crystal structure and magnetic properties of the trinuclear nickel(II) complex bis[(mu-thiocyanato-N)bis(mu-pyridazine-N-1,N-2)bis(thiocyanato-N)(pyridaz ine-N-1)nickel(II)- N,N-1,N-1 ']nickel(II)

Cano J.; Lloret F.; Julve M.; De Munno G.

首页> 外文期刊>Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics >Synthesis crystal structure and magnetic properties of the trinuclear nickel(II) complex bis[(mu-thiocyanato-N)bis(mu-pyridazine-N-1,N-2)bis(thiocyanato-N)(pyridaz ine-N-1)nickel(II)- N,N-1,N-1 ']nickel(II)

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Synthesis crystal structure and magnetic properties of the trinuclear nickel(II) complex bis[(mu-thiocyanato-N)bis(mu-pyridazine-N-1,N-2)bis(thiocyanato-N)(pyridaz ine-N-1)nickel(II)- N,N-1,N-1 ']nickel(II)

机译：三核镍（II）复合物（II）复合物的合成晶体结构和磁性化合物[（MU-硫氰酸根-N-1，N-2）双（硫氰酸盐-N-N）（Pyrodaz Ine-N-1 ）镍（II） - N，N-1，N-1']镍（II）

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Unusual single N-bridging thiocyanato and double pyridazine (pdz) bridges occur in the linear trinuclear nickel(II) complex of formula [Ni-3(pdz)(6)(NCS)(6)]. The compound exhibits a quasi Curie law behavior, the antiferromagnetic coupling through the double 1,2-diazine links being nearly compensated by the ferromagnetic exchange through the single N-bridging thiocyanato. [References: 37]

机译：异常的单桥硫氰酸盐和双哒哒嗪（PDZ）桥在式[Ni-3（PDZ）（6）（NCS）（6）]的线性三核镍（II）络合物中发生。该化合物表现出准居里法行为，通过双桥接通过单桥硫代氰酸盐几乎通过铁磁交换来补偿双1,2-二嗪环的反铁磁偶联。 [参考：37]

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来源
《Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics》 |2000年第7期|共4页
作者
Cano J.; Lloret F.; Julve M.; De Munno G.;
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作者单位

Univ Calabria Dipartimento Chim I-87030 Cosenza Italy .;

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正文语种 eng
中图分类化学;
关键词
Magnetostructural correlations; Bridging thiocyanate; Copper(ii) complexes; Dinuclear complexes; Molecular-structure; Pyridazine pydz; Metal-complexes; Azide bridge; Ligands; Transition;

机译：磁性结构相关;桥面硫氰酸酯;铜（II）复合物;金核络合物;分子结构;哒嗪pydz;金属配合物;叠氮桥;配体;过渡;

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1. Synthesis crystal structure and magnetic properties of the trinuclear nickel(II) complex bis[(mu-thiocyanato-N)bis(mu-pyridazine-N-1,N-2)bis(thiocyanato-N)(pyridaz ine-N-1)nickel(II)- N,N-1,N-1 ']nickel(II) [J] . Cano J., Lloret F., Julve M., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2000,第7期

机译：三核镍（II）复合物（II）复合物的合成晶体结构和磁性化合物[（MU-硫氰酸根-N-1，N-2）双（硫氰酸盐-N-N）（Pyrodaz Ine-N-1 ）镍（II） - N，N-1，N-1']镍（II）
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Synthesis crystal structure and magnetic properties of the trinuclear nickel(II) complex bis[(mu-thiocyanato-N)bis(mu-pyridazine-N-1,N-2)bis(thiocyanato-N)(pyridaz ine-N-1)nickel(II)- N,N-1,N-1 ']nickel(II)

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