Dimeric and monomeric fac-rhenium(I)tricarbonyl complexes containing 2-(imidazo[1,2-a]pyridin-2-yl)phenolate

Saxena Priya; Shankar Bhaskaran; Sathiyendiran Malaichamy

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Dimeric and monomeric fac-rhenium(I)tricarbonyl complexes containing 2-(imidazo[1,2-a]pyridin-2-yl)phenolate

机译：含2-（咪唑并[1,2-a]吡啶-2-基）苯酚酸酯的二聚和单体fac-hen（I）三羰基配合物

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The solvothermal treatment of Re-2(CO)(10) with 2-(imidazo[1,2-a]pyridin-2-yl)phenol (IPPOH) resulted in a dimer, [fRe(C0)312(IPP0)21 (1). Monomeric complexes [fRe(CO)(31)(IPPO)(L)] (L = pyridine for 2; L = 4dimethylaminopyridine for 3) were obtained by treatment of Re-2(CO)(10), IPPOH and a nitrogen donor. Complexes 1-3 were characterized by single crystal X-ray diffraction, analytical and spectroscopic techniques. (C) 2015 Elsevier BY. All rights reserved.

机译：用2-（咪唑并[1,2-a]吡啶-2-基）苯酚（IPPOH）溶剂处理Re-2（CO）（10），得到二聚体，[fRe（C0）312（IPP0）21 （1）。单体配合物[fRe（CO）（31）（IPPO）（L）]（L =吡啶为2; L = 4二甲基氨基吡啶为3）通过处理Re-2（CO）（10），IPPOH和氮供体而获得。配合物1-3通过单晶X射线衍射，分析和光谱技术表征。（C）2015 Elsevier BY。版权所有。

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《Journal of Organometallic Chemistry》 |2015年第null期|共8页
作者
Saxena Priya; Shankar Bhaskaran; Sathiyendiran Malaichamy;
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Complex; 2-(Imidazo1; 2-alphapyridin-2-yl)phenol; Rhenium; Pyridine; Dimethylaminopyridine;

机译：配合物;2-（咪唑并[1;2-α]吡啶-2-基）苯酚;ium;吡啶;二甲基氨基吡啶;

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Dimeric and monomeric fac-rhenium(I)tricarbonyl complexes containing 2-(imidazo[1,2-a]pyridin-2-yl)phenolate

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