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Synthesis and electrical properties of uniform silver nanoparticles for electronic applications

机译:电子应用中均匀银纳米粒子的合成及电性能

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Silver nanoparticles are considered to apply a silver paste for electrode because of their high conductiv_ity. However, the dispersion of silver nanoparticles in electronically conductive adhesives (ECAs) restricts them used as conductive fillers. A simple method had enabled the synthesis of silver nanoparticles by reducing silver nitrate with ethanol in the presence of poly(N-vinylpyrr_olidone) (PVP). Reaction conditions, such as silver nitrate concentration, PVP concentration, reaction time, and reaction temperature, had been studied. Fine dispersion and narrow size distribution of silver nanoparticles were obtained. They were added to ECAs by re-dispersing them in ethanol while it was used as the diluent to adjust the volatility of ECAs, preventing them from the aggregation and increasing the chance to fill the gaps between silver flakes. This proposed process offers the possibility to effectively use these synthesized silver nanoparticles for improving the conductivity of ECAs.
机译:银纳米颗粒由于其高电导率而被认为可将银浆用于电极。然而,银纳米颗粒在导电胶(ECA)中的分散限制了它们用作导电填料。一种简单的方法能够通过在聚(N-乙烯基吡咯烷酮)(PVP)存在下用乙醇还原硝酸银来合成银纳米颗粒。研究了硝酸银浓度,PVP浓度,反应时间和反应温度等反应条件。获得了银纳米颗粒的精细分散和窄尺寸分布。通过将它们重新分散在乙醇中而将它们添加到ECA中,同时将其用作稀释剂以调整ECA的挥发性,防止它们聚集并增加填充薄片状薄片之间的空隙的机会。该提出的方法提供了有效地使用这些合成的银纳米颗粒以改善ECA的电导率的可能性。

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