High-pressure and high-temperature transformation of Pb(II)-natrolite to Pb(II)-lawsonite

Im Junhyuck; Lee Yongmoon; Blom Douglas A.; Vogt Thomas; Lee Yongjae

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High-pressure and high-temperature transformation of Pb(II)-natrolite to Pb(II)-lawsonite

机译：Pb（II）-钠沸石向Pb（II）-钠钠钙石的高温高压转变

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We report on high-pressure and high-temperature chemical transformations of Pb2+-exchanged natrolite (Pb-NAT, Pb8Al16Si24O80.16H(2)O) using a combination of in situ synchrotron X-ray powder diffraction and ex situ HAADF-STEM real space imaging. Three high-pressure polymorphs of natrolites (Pb-NAT-I, II, III) are observed via step-wise pressure-induced hydrations (PIH) up to 4.5 GPa, during which the number of H2O molecules located inside the natrolite channel increases from 16 to 40 H2O per unit-cell. At 4.5 GPa after heating the high-pressure Pb-NAT-III phase at 200 degrees C a reconstructive phase transits into a lawsonite phase (Pb-LAW, Pb4Al8Si8O28(OH)8.4H(2)O) with an orthorhombic space group Pbnm and a = 5.8216(9), b = 9.114(1) and c = 13.320(1) angstrom is obseed. The structure of the recovered Pb-LAW phase was characterized using Rietveld refinement of the in situ synchrotron X-ray powder diffraction data and HAADF-STEM real space imaging. In the recovered Pb-LAW phase the Pb2+ content is close to 42 wt% and as bond valence approximations reveal the Pb2+ cations are more tightly coordinated to the framework oxygen atoms than originally in the natrolite phase.

机译：我们使用原位同步加速器X射线粉末衍射和非原位HAADF-STEM实空间相结合的报告，对Pb2 +交换的钠沸石（Pb-NAT，Pb8Al16Si24O80.16H（2）O）进行高压和高温化学转化成像。通过逐步的压力诱导水合作用（PIH）观察到高达4.5 GPa的三种钠沸石的高压多晶型物（Pb-NAT-I，II，III），在此期间位于钠沸石通道内的H2O分子数量从每单位电池16至40 H2O。在将高压Pb-NAT-III相加热到200摄氏度后，在4.5 GPa下，重构相转变为具有正交晶空间群Pbnm和Pbnm的钙钛矿相（Pb-LAW，Pb4Al8Si8O28（OH）8.4H（2）O）。 a = 5.8216（9），b = 9.114（1），c = 13.320（1）埃。使用Rietveld精制原位同步加速器X射线粉末衍射数据和HAADF-STEM真实空间成像来表征回收的Pb-LAW相的结构。在回收的Pb-LAW相中，Pb2 +含量接近42 wt％，并且随着键合价的近似显示，Pb2 +阳离子与骨架氧原子的配位比最初在钠铝石相中的配位更紧密。

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《Dalton transactions: An international journal of inorganic chemistry》 |2016年第4期|共9页
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Im Junhyuck; Lee Yongmoon; Blom Douglas A.; Vogt Thomas; Lee Yongjae;
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1. High-pressure and high-temperature transformation of Pb(II)-natrolite to Pb(II)-lawsonite [J] . Im Junhyuck, Lee Yongmoon, Blom Douglas A., Dalton transactions: An international journal of inorganic chemistry . 2016,第4期

机译：Pb（II）-钠沸石向Pb（II）-钠钠钙石的高温高压转变
2. Thermal transformation of 1D-Pb(en)_2Cl_2to 3D-PbCl_2 via 2D-Pb(en)Cl_2and their substantial modification of the coordination environment on Pb(II) [J] . Cho Y., Kim S., Pyo S., Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2010,第9期

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机译：国家造船研究计划，任务s-20，造船标准汇编，子任务III国外造船标准中期报告。

High-pressure and high-temperature transformation of Pb(II)-natrolite to Pb(II)-lawsonite

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