Pulse Microwave Deposition of Cobalt Oxide Nanoparticles on Graphene Nanosheets as Anode Materials for Lithium Ion Batteries

摘要

We report the high capacity, superior rate capability, and excellent cyclic stability of graphene nanosheets (GNs) decorated with Co3O4 nanoparticles as anodes in Li-ion batteries. A pulse microwave-assisted (MA) polyol method (total period: 30 min) is adopted to deposit cobalt oxides onto the GNs in water and ethylene glycol (EG), forming two types of Co3O4@GN hybrids. The selection of solvent in the MA process plays a central role in affecting the crystallinity, dispersion, and particle size of cobalt oxide particles. The resulting Co3O4@GN hybrid, prepared by the MA method in EG, shows a homogeneous dispersion of Co3O4 nanocrystals with an average size of 10 nm. The Co3O4@GN hybrid displays advantages of high reversible capacity, excellent cycleability, and high rate capability. This improved cyclic performance can be attributed to the formation of a three-dimensional GN framework decorated with Co3O4 nanocrystals, leading to fast diffusion of Li ions (diffusion coefficient: 5.82 x 10~(-12) cm~2 s~(-1)) and low internal resistance (equivalent series resistance: 92.2 Ω) determined by electrochemical impedance spectroscopy. With its ease of MA fabrication and good performance, the Co3O4@GN hybrid will hold promise in practical Li-ion batteries.