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首页> 外文期刊>The Journal of Chemical Physics >Continuum limit semiclassical initial value representation for dissipative systems
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Continuum limit semiclassical initial value representation for dissipative systems

机译:耗散系统的连续极限半经典初值表示

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In this paper, we consider a dissipative system in which the system is coupled linearly to a harmonic bath. In the continuum limit, the bath is defined via a spectral density and the classical system dynamics is given in terms of a generalized Langevin equation. Using the path integral formulation and factorized initial conditions, it is well known that one can integrate out the harmonic bath, leaving only a path integral over the system degrees of freedom. However, the semiclassical initial value representation treatment of dissipative systems has usually been limited to a discretized treatment of the bath in terms of a finite number of bath oscillators. In this paper, the continuum limit of the semiclassical initial value representation is derived for dissipative systems. As in the path integral, the action is modified with an added nonlocal term, which expresses the influence of the bath on the dynamics. The first order correction term to the semiclassical initial value approximation is also derived in the continuum limit. (c) 2007 American Institute of Physics.
机译:在本文中,我们考虑了一个耗散系统,其中该系统线性耦合到谐波浴。在连续性极限中,通过频谱密度定义熔池,并根据广义Langevin方程给出经典的系统动力学。使用路径积分公式和因式分解的初始条件,众所周知,可以积分谐波浴,仅在系统自由度上留下路径积分。但是,耗散系统的半经典初始值表示处理通常仅限于有限数量的镀浴振荡器,仅用于镀浴的离散处理。本文推导了耗散系统的半经典初始值表示的连续极限。与路径积分一样,用添加的非局部项来修改动作,该非局部项表示浴对动力学的影响。半连续初始值近似值的一阶校正项也来自连续极限。 (c)2007年美国物理研究所。

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