首页> 外文期刊>The Journal of Chemical Physics >Continuum limit frozen Gaussian approximation for the reduced thermal density matrix of dissipative systems
【24h】

Continuum limit frozen Gaussian approximation for the reduced thermal density matrix of dissipative systems

机译:耗散系统热密度矩阵的连续极限冻结高斯逼近

获取原文
获取原文并翻译 | 示例
           

摘要

A continuum limit frozen Gaussian approximation is formulated for the reduced thermal density matrix for dissipative systems. The imaginary time dynamics is obtained from a novel generalized Langevin equation for the system coordinates. The method is applied to study the thermal density in a double well potential in the presence of Ohmic-like friction. We find that the approximation describes correctly the delocalization of the density due to quantization of the vibrations in the well. It also accounts for the friction induced reduction of the tunneling density in the barrier region.
机译:为耗散系统的降低的热密度矩阵制定了一个连续极限冻结高斯近似。虚时动力学是从系统坐标的新型广义Langevin方程获得的。该方法用于研究类似欧姆阻摩的双势阱中的热密度。我们发现,由于井中振动的量化,近似值正确地描述了密度的离散化。这也说明了摩擦引起的势垒区中隧穿密度的降低。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱:kefu@zhangqiaokeyan.com

京公网安备:11010802029741号 ICP备案号:京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有
  • 客服微信

  • 服务号