首页> 外文期刊>The Journal of Chemical Physics >Liquid-to-crystal nucleation: Automated lag-time apparatus to study supercooled liquids
【24h】

Liquid-to-crystal nucleation: Automated lag-time apparatus to study supercooled liquids

机译:液晶结晶成核:自动滞后装置研究过冷液体

获取原文
获取原文并翻译 | 示例
           

摘要

The statistics of liquid-to-crystal nucleation are studied using an automated lag-time apparatus. A single 500 #mu#L sample of distilled water is repeatedly supercooled to fixed temperature below its equilibrium freezing temperature, held until freezing occurred, and then thawed. Our raw data is then a set of approximately 300 lag-times for each of three set supercooling temperatures. In each case, a small insoluble AgI crystalwas added to ensure heterogeneous nucleation and average nucleation temperatures around #DELTA#T=8 K. The distribution of lag-times is analyzed, and shown to be well approximated by a single exponential decay, with average lag-times in the range of 1000-3000 seconds. This average lag-time decreases markedly at deeper levels of supercooling, and for the present data, this decrease is fit equally well by exponential, power law decay, and classical nucleation functional forms.
机译:使用自动滞后时间设备研究了液晶成核的统计数据。将单个500#mu#L蒸馏水样品反复过冷至低于其平衡冷冻温度的固定温度,一直保持到发生冷冻,然后解冻。然后,对于三个设定的过冷温度,我们的原始数据是一组大约300个滞后时间。在每种情况下,都添加一个小的不溶性AgI晶体,以确保在#DELTA#T = 8 K附近形成异相成核和平均成核温度。分析了滞后时间的分布,并显示出通过单次指数衰减可以很好地近似,平均滞后时间在1000-3000秒的范围内。在较深的过冷度下,该平均滞后时间显着降低,并且对于当前数据,该降低同样适用于指数,幂律衰减和经典成核功能形式。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱:kefu@zhangqiaokeyan.com

京公网安备:11010802029741号 ICP备案号:京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有
  • 客服微信

  • 服务号