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Elastic moduli renormalization self-interacting stretchable polyelectrolytes

机译:弹性模量重归一化自相互作用可拉伸聚电解质

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We study the effect of intersegment interactions on the effective bendin and stretching moduli of a semiflexible polymer chain with a finite s tretching modulus. For an interaction potential of a screened Debye-Huckel type, renormalization of the strecching modulus is derived on the same level of approximation as the celebrated Odijk-Skolnick-Fixman result for the bending modulus. The presence of mesoscopic intersegment interaction potentials couples the bending and strecching moduli in a manner different from that predicted by the macroscopic elasticity theory. We thus advocate a fundamental change in the perspective regarding the dependence of elastic moduli of a flexible polyelectrolyte on the ionic conditions:stretchability. The theory presented here and its consequences compare facvorably with recent experments on DNA bending and styretching at not too low salt conditions
机译:我们研究了段间相互作用对具有有限s拉伸模量的半柔性聚合物链的有效弯曲和拉伸模量的影响。对于筛选的Debye-Huckel类型的相互作用势,应以与著名的弯曲模量Odijk-Skolnick-Fixman结果相同的近似水平得出拉伸模量的重新归一化。介观节间相互作用势的存在以与宏观弹性理论所预测的方式不同的方式将弯曲模量和拉伸模量耦合。因此,我们提倡关于挠性聚电解质的弹性模量对离子条件:可拉伸性的依赖性的观点的根本改变。本文介绍的理论及其结果与近期在盐浓度不太低的情况下进行DNA弯曲和定型的实验相比具有优势

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