Enantioselective syntheses of diarylheptanoids (2R,4S,6R)-2-(4-hydroxyphenethyl)-6-(4-hydroxyphenyl) tetrahydro-2H-pyran-4-ol and (3R,5R)-1,7-bis(4-hydroxyphenyl)heptane-3,5-diol

Yadav Jhillu Singh; Gyanchander Eppa; Bujaranipalli Sheshurao; Das Saibal

首页> 外文期刊>Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry >Enantioselective syntheses of diarylheptanoids (2R,4S,6R)-2-(4-hydroxyphenethyl)-6-(4-hydroxyphenyl) tetrahydro-2H-pyran-4-ol and (3R,5R)-1,7-bis(4-hydroxyphenyl)heptane-3,5-diol

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Enantioselective syntheses of diarylheptanoids (2R,4S,6R)-2-(4-hydroxyphenethyl)-6-(4-hydroxyphenyl) tetrahydro-2H-pyran-4-ol and (3R,5R)-1,7-bis(4-hydroxyphenyl)heptane-3,5-diol

机译：二芳基庚类化合物（2R，4S，6R）-2-（4-羟基苯乙基）-6-（4-羟基苯基）四氢-2H-吡喃-4-醇和（3R，5R）-1,7-bis（4）的对映选择性合成-羟基苯基）庚烷-3,5-二醇

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The first total syntheses of diarylheptanoid natural products (2R,4S,6R)-2-(4-hydroxyphenethyl)-6-(4-hydroxyphenyl) tetrahydro-2H-pyran-4-ol (4) and (3R,5R)-1,7-bis (4-hydroxyphenyl)heptane-3,5-diol (12) were accomplished using substrate selective hydrogenation, ring cleavage of tetrahydropyran ring, and Keck-Maruoka allylation as the key synthetic steps. (C) 2015 Elsevier Ltd. All rights reserved.

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《Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry》 |2015年第11期|共3页
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Yadav Jhillu Singh; Gyanchander Eppa; Bujaranipalli Sheshurao; Das Saibal;
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Diarylheptanoids; THP ring; Substrate selective hydrogenation; Dihydropyranone; Keck-Maruoka allylation;

机译：二芳基庚烷;THP环;底物选择性氢化;二氢吡喃酮;Keck-Maruoka烯丙基化;

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1. Enantioselective syntheses of diarylheptanoids (2R,4S,6R)-2-(4-hydroxyphenethyl)-6-(4-hydroxyphenyl) tetrahydro-2H-pyran-4-ol and (3R,5R)-1,7-bis(4-hydroxyphenyl)heptane-3,5-diol [J] . Yadav Jhillu Singh, Gyanchander Eppa, Bujaranipalli Sheshurao, Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2015,第11期

机译：二芳基庚类化合物（2R，4S，6R）-2-（4-羟基苯乙基）-6-（4-羟基苯基）四氢-2H-吡喃-4-醇和（3R，5R）-1,7-bis（4）的对映选择性合成-羟基苯基）庚烷-3,5-二醇
2. Studies on the transformation of nitrosugars into iminosugars III: synthesis of (2R,3R,4R,5R,6R)-2-(hydroxymethyl)azepane-3,4,5,6-tetraol and (2R,3R,4R,5R,6S)-2-(hydroxymethyl)azepane-3,4,5,6-tetraol [J] . Amalia M. Estevez, Raquel G. Soengas, Jose M. Otero, Tetrahedron, Asymmetry: The International Journal for Repid Publication on all Aspects of Asymmetry in Orgainc, Inorganic, Organometallic, Physical and Bio-Organic Chemistry . 2010,第1期

机译：硝化糖向亚氨基糖转化的研究III：（2R，3R，4R，5R，6R）-2-（羟甲基）氮杂环庚烷-3,4,5,6-四醇和（2R，3R，4R，5R， 6S）-2-（羟甲基）氮杂环庚烷-3,4,5,6-四醇
3. The first stereoselective total synthesis of a naturally occurring bioactive diarylheptanoid, (3R,6E)-1,7-bis(4-hydroxyphenyl)hept-6-en-3-ol, through two different approaches [J] . Kashanna J., Jangili P., Kumar R.A., Helvetica chimica acta . 2012,第9期

机译：天然存在的生物活性二芳基庚烷，（3R，6E）-1,7-双（4-羟苯基）庚-6-en-3-ol的首次立体选择性全合成，通过两种不同的方法
4. 5-{(2S,3R,4S,5S,6R)-3,4-Dihydroxy-6-hydroxymethyl-3-[(2S,3R,4R,5R,6S)-3,4,5-trihydroxy-6-methyltetrahydropyran-2-yloxy]tetrahydropyran-2-yloxy}-7-hydroxy-2-(4-hydroxyphenyl)chromen-4-one monohydrate [O] . Shengyang Niu, Haiyan Gao, Airong Wang, 2008

机译：5 - {（2s，3R，4s，5s，6R）-3,4-二羟基-6-羟甲基-3 - [（2s，3R，4R，5R，6s）-3,4,5-三羟基-6-甲基四氢吡喃-2-基氧基]四氢吡喃-2-基氧基} -7-羟基-2-（4-羟基苯基）苯并吡喃-4-酮一水合物

Enantioselective syntheses of diarylheptanoids (2R,4S,6R)-2-(4-hydroxyphenethyl)-6-(4-hydroxyphenyl) tetrahydro-2H-pyran-4-ol and (3R,5R)-1,7-bis(4-hydroxyphenyl)heptane-3,5-diol

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