Heptakis-6-(5-methylene-thioureido-5'-methyl-2,2'-bipyridyl)-beta-cyclodextrin: synthesis and metal complexation study

Romain Heck; Alain Marsura

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Heptakis-6-(5-methylene-thioureido-5'-methyl-2,2'-bipyridyl)-beta-cyclodextrin: synthesis and metal complexation study

机译：Heptakis-6-（5-亚甲基-硫脲基5'-甲基-2,2'-联吡啶基）-β-环糊精：合成和金属络合研究

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A new heptapode heptakis-6-(5-methylene-thioureido-5'-methyl-2,2'-bipyridyl)-beta-cyclodextrin was prepared and its complexation properties towards metal cations were investigated. Substituting the urea functions by the corresponding thioureas promoted the inversion of the metal coordination selectivity. Preliminary results showed the heptapode unable to complex lanthanides but authorise selective complexation of 'soft' and 'borderline' metal cations.

机译：制备了一种新的七肽-6-（5-亚甲基-硫脲基-5'-甲基-2,2'-联吡啶基）-β-环糊精，并研究了其对金属阳离子的络合性能。用相应的硫脲取代尿素功能促进了金属配位选择性的转化。初步结果表明，该七足动物不能与镧系元素络合，但可以选择性地络合“软”和“边界”金属阳离子。

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《Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry 》 |2003年第8期| 共4页
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Romain Heck; Alain Marsura;
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1. Heptakis-6-(5-methylene-thioureido-5'-methyl-2,2'-bipyridyl)-beta-cyclodextrin: synthesis and metal complexation study [J] . Romain Heck, Alain Marsura Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2003 ,第8期

机译：Heptakis-6-（5-亚甲基-硫脲基5'-甲基-2,2'-联吡啶基）-β-环糊精：合成和金属络合研究
2. Synthesis, Composition, Studies on the Transition Metal Complexes of the Schiff Base Metal Complexes Derived from 4-chloro phenylenediamine, furfuraldehyde and 2,2' bipyridyl with DNA fragments [J] . V.S. Saravana Mani, R. Narayanasamy, S.Vijyalakshmi Advances in aerospace science and applications . 2016 ,第1期

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3. Synthesis, Composition, Studies on the Transition Metal Complexes of the Schiff Base Metal Complexes Derived from 4-chloro phenylenediamine, furfuraldehyde and 2,2' bipyridyl with DNA fragments [J] . V.S. Saravana Mani, R. Narayanasamy, S.Vijyalakshmi International Journal of Applied Chemistry . 2015 ,第2期

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4. Construction and Structural Analysis of a Cd11L6 22+ Hexameric Supramolecular Cage Complex Composed of a Porphyrin Ligand having 5-Methyl-2,2’-bipyridyl Units [C] . Fumiya Iizuka, Hitoshi Ube, Mitsuhiko Shionoya 日本化学会春季年会講演予稿集 . 2018

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5. Studies of asymmetric allylic oxidation of cyclic olefins catalyzed by copper(I) bisoxazoline, biaryloxazoline and 2,2'-bipyridyl complexes. [D] . Zhou, Ziniu. 2005

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6. Synthesis Photophysical and Electrochemical Properties of a Mixed Bipyridyl-Phenanthrolyl Ligand Ru(II) Heteroleptic Complex Having trans-2-Methyl-2-butenoic Acid Functionalities [O] . Adewale O. Adeloye 2011

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Heptakis-6-(5-methylene-thioureido-5'-methyl-2,2'-bipyridyl)-beta-cyclodextrin: synthesis and metal complexation study

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