Tetrazole thiolate/disulfide organic redox couples carrying long alkyl groups in dye-sensitized solar cells with Pt-free electrodes

摘要

Colorless tetrazole thiolate/sulfide redox couples carrying long alkyl groups, such as n-butyl, n-hexyl, and n-octyl groups, were synthesized as electrolytes in iodine/iodide-free dye-sensitized solar cells (DSSCs). Among N719/TiO_2-based DSSCs employing these highly soluble redox couples for 3- methoxypropionitrile (3-MPN) and ionic liquid with PEDOT counter electrode, the DSSC with n-hexyl redox analogue gave an optimized η value of 4.32%. An observed respectable quantum efficiency for 400-500 nm light is in sharp contrast to the decreased performance for iodine/iodide systems that originates from the substantial light absorption of iodine. On the other hand, the redox possessing n- octyl group significantly lowered the cell performance, which could be a result of the much increased resistance of electrolyte diffusion in the DSSC.